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A new Cd(II) coordination polymer constructed by a flexible carboxylate ligand

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Abstract

A new two-dimensional Cd(II) coordination polymer, [Cd(dtb)(CH3OH)] n (H 2 DTNB = 5,5′-dithiobis(2-nitrobenzoic acid), has been synthesized by solvothermal method, and characterized by elemental analysis, IR and single-crystal X-ray diffraction analysis. The complex crystallizes in the orthorhombic Pbca space group, with a = 15.1365(19) Å, b = 7.6198(10) Å, c = 31.761(4) Å, β = 90°, V = 3663.2(8) Å3, Z = 8, Mr = 538.77, D c = 1.954 g/cm3 and F(000) = 2128. The final R = 0.040 and wR = 0.0866 for 3603 observed reflections with I > 2σ(I). In the complex, the Cd(II) ion is coordinated with six oxygen atoms from four carboxylate groups of distinct DTNB ligands and one methanol molecule. The adjacent Cd centers are interconnected by the flexible carboxylate ligand to form a two-dimensional (2D) structure.

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Authors and Affiliations

  1. College of Chemical Engineering, Jiangsu Key Lab of Biomass-Based Green Fuels and Chemicals, Nanjing Forestry University, Nanjing, 210037, P. R. China

    X.-M. Yuan, D. Sun & H.-J. Xu

  2. Department of Chemistry, Nanchang University, Nanchang, 330031, P. R. China

    D.-P. Li

Authors
  1. X.-M. Yuan
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  2. D. Sun
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  3. D.-P. Li
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  4. H.-J. Xu
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Corresponding author

Correspondence to H.-J. Xu.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 5, pp. 1087-1091, June-July, 2016.

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Yuan, XM., Sun, D., Li, DP. et al. A new Cd(II) coordination polymer constructed by a flexible carboxylate ligand. J Struct Chem 57, 1036–1040 (2016). https://doi.org/10.1134/S0022476616050279

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  • DOI: https://doi.org/10.1134/S0022476616050279

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