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Crystal structure of a new manganese(III) complex with tetradentate Schiff base N,N′-O-phenylenebis(4-methoxysalicylideneimine)

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Abstract

A new manganese(III) complex [Mn(L)(NCS)] (1) is synthesized from the Schiff base ligand N,N′-O-phenylenebis(4-methoxysalicylideneimine) (H2L: derived from the condensation of 4-methoxy salicylaldehyde with O-phenylene-diamine) with Mn(NO3)2∙4H2O and KSCN in a methanol/water solvent mixture. This complex is characterized by elemental analysis, FT-IR and single crystal X-ray diffraction. It crystallizes in a monoclinic system, with space group P21/c and four molecules in the unit cell (Z = 4). The crystal structure shows [Mn(L)(NCS)] units joined together by the Mn∙∙∙S secondary bonding interaction (SBI) to form infinite zigzag chain structures.

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Authors and Affiliations

  1. Department of Chemistry, Saveh Branch, Islamic Azad University, Saveh, Iran

    A. Ghaemi, B. Keyvani & S. Zarei

  2. Department of Chemistry, K.N. Toosi University of Technology, Tehran, Iran

    S. Rayati

  3. Department of Chemistry, Shahid Beheshti University, G.C., Evin, Tehran, 1983963113, Iran

    B. Notash

Authors
  1. A. Ghaemi
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  2. B. Keyvani
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  3. S. Rayati
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  4. S. Zarei
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  5. B. Notash
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Corresponding author

Correspondence to A. Ghaemi.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 5, pp. 1078-1081, June-July, 2016.

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Ghaemi, A., Keyvani, B., Rayati, S. et al. Crystal structure of a new manganese(III) complex with tetradentate Schiff base N,N′-O-phenylenebis(4-methoxysalicylideneimine). J Struct Chem 57, 1027–1030 (2016). https://doi.org/10.1134/S0022476616050255

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  • DOI: https://doi.org/10.1134/S0022476616050255

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