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Proton state in hydrated fluoro-substituted brownmillerites Ba2In2O5–0.5y F y ∙nН2О

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Abstract

Solid solutions Ba2In2O5–0.5y F y with the structure of brownmillerite are studied by IR and 1Н MAS NMR spectroscopy. During the fluorine doping, the nearest oxygen environment of indium atoms is distorted and a part of In–O bonds is shortened. It is shown that partial fluoride ion substitution for oxygen atoms results in an increase in the proton mobility in hydrated Ba2In2O5–0.5y F y ∙nН2О phases.

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Authors and Affiliations

  1. Yeltsin Ural Federal University, Ekaterinburg, Russia

    I. E. Animitsa, N. A. Tarasova & Ya. V. Baklanova

  2. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Ekaterinburg, Russia

    T. A. Denisova

Authors
  1. I. E. Animitsa
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  2. N. A. Tarasova
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  3. T. A. Denisova
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  4. Ya. V. Baklanova
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Correspondence to I. E. Animitsa.

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__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 5, pp. 959-965, June-July, 2016.

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Animitsa, I.E., Tarasova, N.A., Denisova, T.A. et al. Proton state in hydrated fluoro-substituted brownmillerites Ba2In2O5–0.5y F y ∙nН2О. J Struct Chem 57, 910–916 (2016). https://doi.org/10.1134/S0022476616050097

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  • DOI: https://doi.org/10.1134/S0022476616050097

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