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Substituent group effects on the self-assembly of oxovanadium(V) complexes with hydrazone ligands bearing benzoic acid (1-methyl-3-oxobutylidene)hydrazide backbones

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Abstract

An oxo-bridged dinuclear oxovanadium(V) complex, [V2O2(μ-O)(L1)2] (1) [H2L1 = 3-nitrobenzoic acid (1-methyl-3-oxobutylidene)hydrazide], and a mononuclear oxovanadium(V) complex, [VO(OMe)(L2)] (2) [H2L2 = 3-hydroxynaphthalene-2-carboxylic acid (1-methyl-3-oxobutylidene)hydrazide], were prepared by the reactions of [VO(acac)2] with H2L1 and H2L2, respectively, in methanol. Both complexes were characterized by elemental analysis, IR spectra, and single crystal X-ray crystallography. The crystal of 1 crystallizes in the monoclinic space group P2/n, with a = 13.116(3) Å, b = 7.597(2) Å, c = 13.927(2) Å, β = 104.851(2)°, V = 1341.4(5) Å3, Z = 2. The crystal of 2 crystallizes in the triclinic space group \(P\overline 1 \), with a = 7.897(2) Å, b = 9.690(2) Å, c = 11.576(3) Å, α = 86.405(2)°, β = 70.597(2)°, γ = 85.991(2)°, V = = 832.7(3) Å3, Z = 2. The V atoms in the complexes have square pyramidal environment. The substituent groups attached to the aromatic rings can influence the self-assembly of the complexes.

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Authors and Affiliations

  1. Engineering Research Center for Clean Production of Textile Printing, Ministry of Education, Wuhan Textile University, Wuhan, 430073, P. R. China

    Y.-M. Cui, D. Yang, Q. Wang & P. Zhang

  2. Chinese Sturgeon Institute, China Three Gorges Corporation, Yichang, 443100, P. R. China

    W. Guo

Authors
  1. Y.-M. Cui
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  2. D. Yang
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  3. W. Guo
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  4. Q. Wang
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  5. P. Zhang
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Corresponding author

Correspondence to Y.-M. Cui.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 877-881, May-June, 2016.

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Cui, YM., Yang, D., Guo, W. et al. Substituent group effects on the self-assembly of oxovanadium(V) complexes with hydrazone ligands bearing benzoic acid (1-methyl-3-oxobutylidene)hydrazide backbones. J Struct Chem 57, 840–844 (2016). https://doi.org/10.1134/S002247661604034X

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  • DOI: https://doi.org/10.1134/S002247661604034X

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