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Crystal structure of two homochiral metal-organic polymers based on S-3,3-dimethyllactic acid

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Abstract

By heating of an aqueous solution of zinc(II) or cobalt(II) acetates, 4,4-bipyridyl (bpy), and S-3,3-dimethyl hydroxypropionic acid (H2dml) two homochiral coordination polymers [Zn(H2O)(bpy)(Hdml)](CH3COO)∙ ∙2H2O (1) and [Co(H2O)(bpy)(Hdml)2] (2) are obtained. The crystal structure is determined by single crystal X-ray diffraction. Compound 1 has a layered structure and compound 2 has a chain structure.

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Correspondence to V. P. Fedin.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 868-872, May-June, 2016.

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Zavakhina, M.S., Samsonenko, D.G. & Fedin, V.P. Crystal structure of two homochiral metal-organic polymers based on S-3,3-dimethyllactic acid. J Struct Chem 57, 830–834 (2016). https://doi.org/10.1134/S0022476616040326

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  • DOI: https://doi.org/10.1134/S0022476616040326

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