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Crystal structure of novel layered iron arsenate-oxalate (NH4)3K3[Fe2(HAsO4)2(C2O4)4]∙2H2O

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Abstract

A new open-framework structure of iron arsenate-oxalate (NH4)3K3[Fe2(HAsO4)2(C2O4)4]∙2H2O (I) is synthesized by slow evaporation and structurally characterized by single crystal X-ray diffraction methods. It crystallizes in the triclinic space group \(P\overline 1 \) (No. 2), with a = 10.154(4) Å, b = 10.430(4) Å, c = 15.085(7) Å, α = 96.81(3)°, β = 105.04(43)°, γ = 93.93(3)°, V = 1523.7(11) Å3 and Z = 2. Its crystal structure consists of two crystallographically independent bishydrogenarsenato tetraoxalato diiron(III) anions, both located on centres of inversion, while the potassium and ammonium cations and water molecules are located in general positions.These moieties are connected through N–H…O and O–H…O hydrogen bonds to form infinity of layers parallel to the (101) plane, thus leading to a two-dimensional open framework.

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Authors and Affiliations

  1. Université de Tunis El Manar, Faculté des Sciences de Tunis, Laboratoire de Matériaux et Cristallochimie, Tunis, Tunisia

    N. Ouerfelli, H. Chebbi & M. Faouzi Zid

  2. Université de Tunis Carthage, Institut Préparatoire aux Etudes d′Ingénieur de Bizerte, Bizerte, Tunisia

    N. Ouerfelli

  3. Université de Monastir, Institut Préparatoire aux Etudes d′Ingénieurs de Monastir, Monastir, Tunisia

    H. Chebbi

Authors
  1. N. Ouerfelli
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  2. H. Chebbi
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  3. M. Faouzi Zid
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Correspondence to H. Chebbi.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 854-857, May-June, 2016.

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Ouerfelli, N., Chebbi, H. & Faouzi Zid, M. Crystal structure of novel layered iron arsenate-oxalate (NH4)3K3[Fe2(HAsO4)2(C2O4)4]∙2H2O. J Struct Chem 57, 815–818 (2016). https://doi.org/10.1134/S0022476616040284

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  • DOI: https://doi.org/10.1134/S0022476616040284

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