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Crystal structure of a new binuclear complex bis(2,4,6,8-tetramethyl-2,4,6,8-tetraazabicyclo(3.3.0)octane-3,7-dione-o,o′)-tetraaqua-hexakis(nitrato-o,o′)-dieuropium(III)

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Abstract

A centrosymmetric binuclear complex of europium(III) nitrate with bicyclic bisurea (2,4,6,8-tetramethyl-2,4,6,8-tetraazabicyclo(3.3.0)octane-3,7-dione, or mebicar, Mk) [Eu(C8H14N4O2)(H2O)2(NO3)3]2 (I) is synthesized and its atomic structure (CIF file CCDC No. 1451437) is determined. The crystals of I are triclinic: space group \(P\overline 1 \), a = 9.8343(4) Å, b = 10.2544(4) Å, c = 10.9411(4) Å, α = 74.366(3)°, β = 67.734(4)°, γ = 67.673(4)°, V = 934.32(7) Å3, ρ(calc.) = 2.03398 g/cm3, Z = 1. The europium atom is coordinated by two oxygen atoms of two Mk molecules connected by a symmetry operation, three bidentate nitrate anions, and two water molecules. The coordination polyhedron of the europium atom is a 10-vertex polyhedron, the Eu…Eu distance is 9.7433(6) Å.

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References

  1. A. U. Karimov, Sots. Klin. Psikhiatr., 17, No. 4, 9 (2007).

    Google Scholar 

  2. A. M. Mannanov, T. T. Shakhabiddinov, and K. N. Khaitov, Pediatriya, 89, No. 6, 127 (2010).

    Google Scholar 

  3. L. A. Lapshina, P. G. Kravchun, and O. C. Shevchenko, Vrach. Prakt., 61, No. 1, 23 (2008).

    Google Scholar 

  4. M. E. Statsenko, O. E. Sporova, N. N. Shilina, et al., Kardiol. Serdechno-Sosudistaya Khir., 4, 41 (2011).

    Google Scholar 

  5. I. N. Skrypnik, A. V. Nevoit, and O. V. Beruk, Vsn. Probl. B?ol. Med., 4, 151 (2007).

    Google Scholar 

  6. S. V. Fedorovich and I. L. Arsentieva, Allergol. Immunol., 8, No. 1, 54 (2007).

    Google Scholar 

  7. A. Yu. Tsivadze, I. S. Ivanova, and I. K. Kireeva, Zh. Neorg. Khim., 31, No. 7, 1780 (1986).

    CAS  Google Scholar 

  8. A. Yu. Tsivadze, I. S. Ivanova, and I. K. Kireeva, Zh. Neorg. Khim., 32, No. 8, 1876 (1987).

    CAS  Google Scholar 

  9. T. S. Khodashova, I. S. Ivanova, I. K. Kireeva, et al., Zh. Neorg. Khim., 34, No. 8, 1972 (1989).

    Google Scholar 

  10. M. A. Porai-Koshits, A. Yu. Tsivadze, I. S. Ivanova, et al., Koord. Khim., 11, No. 9, 1246 (1985).

    CAS  Google Scholar 

  11. L. I. Suvorova, V. A. Eres’ko, and L. V. Epishina, Russ. Chem. Bull., 28, No. 6, 1222 (1979).

    Article  Google Scholar 

  12. A. N. Kravchenko, A. S. Sigachev, and E. Yu. Maksareva, Russ. Chem. Bull., 54, No. 3, 691 (2005).

    Article  CAS  Google Scholar 

  13. G. M. Sheldrick, SHELXS-2014. Program for Crystal Structure Solution, University of Göttingen, Germany (2014).

    Google Scholar 

  14. L. J. Farrugia, Appl. Crystallogr. A, 32, 837 (1999).

    Article  CAS  Google Scholar 

  15. A. I. Grigoriev, Introduction to Vibrational Spectroscopy of Inorganic Compounds [in Russian], MGU, Moscow (1977).

    Google Scholar 

  16. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds, John Wiley and Sons, New York (1963).

    Google Scholar 

  17. Yu. Ya. Kharitonov, Analytical Chemistry. Analytics [in Russian], book 1, Vysshaya Shkola, Moscow (2003).

    Google Scholar 

  18. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, 4th ed., John Wiley and Sons, New York (1986).

    Google Scholar 

  19. H.-B. Burgi and J. D. Dunitz, Structure Correlation, vol. 1, VCH, Weinheim (1994).

    Book  Google Scholar 

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Authors and Affiliations

  1. Taurida Academy of Vernadsky Crimean Federal University, Simferopol, Russia

    E. E. Netreba, E. A. Sarnit, S. V. Shabanov & A. A. Velikozhon

  2. Lobachevsky State University, Nizhny Novgorod, Russia

    N. V. Somov

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  1. E. E. Netreba
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  2. E. A. Sarnit
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  3. S. V. Shabanov
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  4. A. A. Velikozhon
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  5. N. V. Somov
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Correspondence to E. E. Netreba.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 792-797, May-June, 2016.

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Netreba, E.E., Sarnit, E.A., Shabanov, S.V. et al. Crystal structure of a new binuclear complex bis(2,4,6,8-tetramethyl-2,4,6,8-tetraazabicyclo(3.3.0)octane-3,7-dione-o,o′)-tetraaqua-hexakis(nitrato-o,o′)-dieuropium(III). J Struct Chem 57, 754–759 (2016). https://doi.org/10.1134/S0022476616040181

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  • DOI: https://doi.org/10.1134/S0022476616040181

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