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Structures, properties and topologies of two layered compounds based on 2-carboxethyl(phenyl)phosphinic acid

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Abstract

Hydrothermal syntheses of 2-carboxyethyl(phenyl)phosphinic acid (H2CEPPA) with Bi(NO3)3 and Cd(NO3)2 produce two layered complexes [Bi2(μ3-O)(CEPPA)2] n (1) and [Cd(HCEPPA)2] n (2). Compound 1 is comprised of [Bi4(μ3-O)2(POO)4(COO)4] SBUs which grow into a double wave-like 2D layer with–CH2CH2–spacers. Compound 2 crystallizes in the orthorhombic noncentrosymmetric space group Pca21, exhibiting a double lattice-like layer. Through edge-to-face d∙∙∙π stacking, a 3D supramolecular framework is formed based on 2D lattices. Topological analyses indicate that 1 and 2 have sql (or Shubnikov tetragonal plane net) and kgd (or Shubnikov (3.6.3.6) plane net) topological networks respectively. 1 and 2 are isolated as single crystal pure phases, which is confirmed by powder XRD. TGA shows high thermal stabilities with decomposition temperatures of 1 and 2 being 373 and 303°C respectively. The fluorescent spectra exhibit fluorescence quenching in 1 and sharp emission at 292 nm in 2, which is assigned to intraligand emission.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Shaanxi University of Sciences and Technology, Xi′an, Shaanxi, P. R. China

    B. Liu & L. Xu

  2. Key Laboratory of Macromolecular Science of Shaanxi Province, School of Chemistry & Chemical Engineering, Shaanxi Normal University, Xi′an, Shaanxi, P. R. China

    Z.-H. Zhang, L. Xu & H. Jiao

Authors
  1. B. Liu
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  2. Z.-H. Zhang
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  3. L. Xu
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  4. H. Jiao
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Corresponding author

Correspondence to L. Xu.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 782-791, May-June, 2016.

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Liu, B., Zhang, ZH., Xu, L. et al. Structures, properties and topologies of two layered compounds based on 2-carboxethyl(phenyl)phosphinic acid. J Struct Chem 57, 744–753 (2016). https://doi.org/10.1134/S002247661604017X

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  • DOI: https://doi.org/10.1134/S002247661604017X

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