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Inorganic architecture based on a {[Ca(H2O)]6[P4W6O34]2}12– building block: Countercation effect on the lattice symmetry

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Abstract

Three new salts of the {[Ca(H2O)]6[P4W6O34]2}12– polyanion, namely (NH4)12{[Ca(H2O)]6∙[P4W6O34]2}∙ ∙24H2O (1), H2[Na(H2O)1.6]10{[Ca(H2O)]6[P4W6O34]2}∙10H2O (2), and [Ca(H2O)5]6{[Ca(H2O)]6∙ ∙[P4W6O34]2}∙11H2O (3) are prepared. The change in the lattice as a function of the countercation and its coordination, specially calcium, is investigated. Full characterization is made by single crystal X-ray diffraction and also UV-visible spectroscopy, FT-IR, thermogravimetric analysis (TGA), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDS).

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References

  1. C. L. Hill, Chem. Rev., 98, 1/2 (1998).

    Article  Google Scholar 

  2. J. M. Clemente-Juan, E. Coronado, and A. Gaita-Arino, Chem. Soc. Rev., 41, 7464–7478 (2012).

    Article  CAS  Google Scholar 

  3. N. Gao, H. Sun, K. Dong, J. Ren, T. Duan, C. Xu, and X. Qu, Nat. Commun., 5 (2014).

    Google Scholar 

  4. L. de Matteis, S. G. Mitchell, and J. M. de la Fuente, J. Mat. Chem. B, 2, 7114–7117 (2014).

    Article  Google Scholar 

  5. S. Liu, H. Möhwald, D. Volkmer, and D. G. Kurth, Langmuir, 22, 1949–1951 (2006).

    Article  CAS  Google Scholar 

  6. S. Mitsui, A. Ogata, H. Yanagie, H. Kasano, T. Hisa, T. Yamase, and M. Eriguchi, Biomed. Pharmacother., 60, 353–358 (2006).

    Article  CAS  Google Scholar 

  7. W. E. G. Müller, X. Wang, and H. C. Schröder (eds.), Biomedical Inorganic Polymers, Springer, Berlin–Heidelberg (2013), pp. 65–116.

    Google Scholar 

  8. Y. Zhang, N. A. W. Holzwarth, and R. T. Williams, Phys. Rev. B, 57, 12738–12750 (1998).

    Article  CAS  Google Scholar 

  9. S. Vidya, S. Solomon, and J. K. Thomas, J. Electron. Mater., 42, 129–137 (2013).

    Article  CAS  Google Scholar 

  10. Z. Xu, Sci. Rep., 3 (2013).

    Google Scholar 

  11. W. Jingping, W. Qiang, and N. Jingyang, Sci. China, Ser. B: Chem., 45, 647–654 (2002).

    Article  Google Scholar 

  12. J. Wang, D. Yang, and J. Niu, J. Coord. Chem., 61, 3651–3658 (2008).

    Article  CAS  Google Scholar 

  13. J. Wang, J. Zhao, P. Ma, J. Ma, L. Yang, Y. Bai, M. Li, and J. Niu, Chem. Commun., 2362–2364 (2009).

    Google Scholar 

  14. D.-Y. Chen, J.-S. Wang, D. Yang, J.-P. Wang, and J.-Y. Niu, Chin. J. Struct. Chem., 29, 940–946 (2010).

    CAS  Google Scholar 

  15. J. Niu, J. Ma, J. Zhao, P. Ma, and J. Wang, Inorg. Chem. Commun., 14, 474–477 (2011).

    Article  CAS  Google Scholar 

  16. A. F. Stepnova, A. V. Oreshkina, G. Z. Kaziev, S. Holguin Quinones, and A. I. Stash, Russ. J. Inorg. Chem., 57, 783–786 (2012).

    Article  CAS  Google Scholar 

  17. K. Cui, F. Li, L. Xu, Y. Wang, Z. Sun, and H. Fu, CrystEngComm, 15, 4721–4729 (2013).

    Article  CAS  Google Scholar 

  18. C. P. Pradeep, D.-L. Long, and L. Cronin, Dalton Trans., 39, 9443–9457 (2010).

    Article  CAS  Google Scholar 

  19. M. A. Khanfar, I. Warad, and M. A. AlDamen, Acta Crystallogr., Sect. E: Struct. Rep. Online, 66, m731/m732 (2010).

    Article  Google Scholar 

  20. S. F. Haddad, M. A. AlDamen, R. D. Willett, and B. Twamley, Acta Crystallogr., Sect. E: Struct. Rep. Online, 60, m76–m78 (2003).

    Article  Google Scholar 

  21. M. Al-Noaimi, M. Sunjuk, M. El-Khateeb, S. F. Haddad, A. Haniyeh, and M. AlDamen, Polyhedron, 42, 66–73 (2012).

    Article  CAS  Google Scholar 

  22. M. Al-Noaimi and M. A. AlDamen, Inorg. Chim. Acta, 387, 45–51 (2012).

    Article  CAS  Google Scholar 

  23. M. Al-Noaimi, R. J. Crutchley, M. AlDamen, A. M. Rawashdeh, M. A. Khanfar, and K. Seppelt, Polyhedron, 30, 2075–2082 (2011).

    Article  CAS  Google Scholar 

  24. I. Warad, M. Al-Noaimi, O. S. Abdel-Rahman, M. AlDamen, B. Hammouti, and T. B. Hadda, Polyhedron, 63, 182–188 (2013).

    Article  CAS  Google Scholar 

  25. J. A. Kafawein, H. K. Juwhari, and M. A. AlDamen, J. Cluster Sci., 1–10 (2015).

  26. M. A. Aldamen and S. F. Haddad, J. Coord. Chem., 64, 4244–4253 (2011).

    Article  CAS  Google Scholar 

  27. C. P. Pradeep, D.-L. Long, C. Streb, and L. Cronin, J. Am. Chem. Soc., 130, 14946/14947 (2008).

    Article  Google Scholar 

  28. A. L. Spek, J. Appl. Crystallogr., 7 (2003).

    Google Scholar 

  29. O. V. Dolomanov, L. J. Bourhis, R. J. Gildea, J. A. K. Howard, and H. Puschmann, J. Appl. Crystallogr., 42, 339–341 (2009).

    Article  CAS  Google Scholar 

  30. G. M. Sheldrick, SHELXL97. Program for the Refinement of Crystal Structures (1997).

    Google Scholar 

  31. F. H. Allen, Acta Crystallogr., B 58, 380–388 (2002).

    Article  Google Scholar 

  32. G. Chiari, Acta Crystallogr., B 46, 717–723 (1990).

    Article  Google Scholar 

  33. C. Rocchiccioli-Deltcheff and R. Thouvenot, Spectrosc. Lett., 12, 127–138 (1979).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, the University of Jordan, Amman, Jordan

    M. A. AlDamen, S. B. Atta & S. F. Haddad

Authors
  1. M. A. AlDamen
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  2. S. B. Atta
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  3. S. F. Haddad
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Correspondence to M. A. AlDamen.

Additional information

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 756-763, May-June, 2016.

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AlDamen, M.A., Atta, S.B. & Haddad, S.F. Inorganic architecture based on a {[Ca(H2O)]6[P4W6O34]2}12– building block: Countercation effect on the lattice symmetry. J Struct Chem 57, 717–724 (2016). https://doi.org/10.1134/S0022476616040132

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  • DOI: https://doi.org/10.1134/S0022476616040132

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