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Crystallographic analysis of sulfides related to bismuthinite Bi2S3

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Abstract

The crystallographic analysis of Bi2S3, CuPbBi5S9, CuPbBi3S6, and CuPbBiS3 compounds, representing a series with a successive replacement of a part of Bi atoms by Pb+Cu, shows that they are characterized by a stable combination of a pseudotetragonal cation framework with a pseudohexagonal anion one, which is common for all structures, within orthorhombic unit cells with n sizes of 11.2 Å, 4 Å, and 11.5 Å. The Bi2S3 cation framework is retained for the heavy Bi+Pb, and additional light Cu fill the available vacant sites without changing its geometry but varying the crystallographic symmetry within the orthorhombic crystal symmetry and unit cells of n standard blocks (11.2×4×11.5 Å3).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. V. Borisov, S. A. Magarill & N. V. Pervukhina

Authors
  1. S. V. Borisov
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  2. S. A. Magarill
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  3. N. V. Pervukhina
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Correspondence to S. A. Magarill.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 742-748, May-June, 2016.

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Borisov, S.V., Magarill, S.A. & Pervukhina, N.V. Crystallographic analysis of sulfides related to bismuthinite Bi2S3 . J Struct Chem 57, 704–709 (2016). https://doi.org/10.1134/S0022476616040119

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  • DOI: https://doi.org/10.1134/S0022476616040119

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