Abstract
(7Li, 1H) NMR and impedance spectroscopy methods are used to study the ion mobility and conductivity in a complex of the composition Li(NH3CH2COO)(NO3) (I), which has a layered crystal structure. The character of ion motions in lithium and proton sublattices with temperature variation is considered; the types of motions and temperature ranges in which they occur are determined. It is found that above 350 K the dominant process in the lithium sublattice of the compound is Li+ ion diffusion. Possible migration paths of lithium ions in the lattice of the compound are analyzed. The specific conductivity of the compound is found to be 2.4×10–6 S/cm at 393 K.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 4, pp. 697-703, May-June, 2016.
Devoted to the 80th anniversary of Professor S. P. Gabuda
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Kavun, V.Y., Udovenko, A.A., Makarenko, N.V. et al. Ion mobility and conductivity in the Li(NH3CH2COO)(NO3) compound. J Struct Chem 57, 658–664 (2016). https://doi.org/10.1134/S0022476616040041
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DOI: https://doi.org/10.1134/S0022476616040041