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Crystal structure of [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O

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Abstract

The structure of [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O is determined by single crystal X-ray diffraction. The crystallographic characteristics are as follows: a = 8.9414(4) Å, b = 14.5330(5) Å, c = 24.9383(9) Å, V = 3240.6(2) Å3, space group Pbca, Z = 8. The Co(III) atoms have a slightly distorted octahedral coordination formed by three nitrogen atoms belonging to nitro groups (Co–Nav is 1.91 Å) and three oxygen atoms belonging to hydroxyl groups (Co–Oav is 1.93 Å). The hydroxyl groups act as μ3-bridges between the metal atoms. The geometric characteristics are analyzed and the packing motif is determined.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    S. P. Khranenko, N. V. Kuratieva, I. V. Korolkov & S. A. Gromilov

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    N. V. Kuratieva, I. V. Korolkov & S. A. Gromilov

Authors
  1. S. P. Khranenko
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  2. N. V. Kuratieva
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  3. I. V. Korolkov
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  4. S. A. Gromilov
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Corresponding author

Correspondence to S. A. Gromilov.

Additional information

Translated from Zhurnal Strukturnoi Khimii, Vol. 57, No. 3, pp. 655-657, March-April, 2016.

Original Russian Text © 2016 S.P. Khranenko, N. V. Kuratieva, I. V. Korolkov, S. A. Gromilov.

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Khranenko, S.P., Kuratieva, N.V., Korolkov, I.V. et al. Crystal structure of [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O. J Struct Chem 57, 625–627 (2016). https://doi.org/10.1134/S0022476616030240

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  • DOI: https://doi.org/10.1134/S0022476616030240

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