Abstract
The crystal and molecular structures of 1-(iodmethyl)silatrane and 1-(iodpropyl)silatrane are determined by X-ray diffraction. The effect of the iodine heteroatom upon silatrane moieties of the molecules through oneand three-carbon chains is studied based on the geometric characteristics of the molecules and the analysis of their packings.
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M. G. Voronkov and V. P. Baryshok, Herald Russ. Acad. Sci., 80, No. 11, 985–992 (2010).
A. V. Garabadzhiu, M. G. Voronkov, G. G. Nyanikova, et al., Dokl. Biol. Sci., 439, No. 6, 838–840 (2011).
A. A. Kemme, Ya. Ya. Bleidelis, V. M. D’yakov, and M. G. Voronkov, J. Struct. Chem., 16, No. 5, 847–850 (1975).
A. A. Kemme, Ya. Ya. Bleidelis, V. M. D’yakov, and M. G. Voronkov, Russ. Chem. Bull., 10, 2400/2401 (1976).
M. G. Voronkov and V. P. Baryshok, Silatranes in Medicine and Agriculture, Publishing House SB RAS, Novosibirsk, Russia (2005).
M. G. Voronkov, V. M. D’yakov, G. A. Samsonova, et al., Russ. Chem. Bull., No. 12, 2794 (1974).
V. M. D’yakov, Ya. A. Lukina, M. G. Voronkov, et al., Russ. Chem. Bull., No. 10, 2366 (1978).
G. M. Sheldrick, Acta Crystallogr., A 64, 112–122 (2008).
A. Yu. Antipin, et al., Mendeleev Commun., 88 (2000).
V. A. Pestunovich, S. V. Kirpichenko, and M. G. Voronkov, in: The Chemistry of Organic Silicon Compounds, Z. Rappoport and Y. Apeloig (eds.), vol. 2, Willey & Sons, N.-Y. (1998), pp. 1447–1537.
Yu. V. Zefirov and P. M. Zorkii, Russ. Chem. Rev., 58, Vol. 5, 713–746 (1989).
M. G. Voronkov, Top. Curr. Chem., 84, 77–135 (1979).
M. G. Voronkov, E. A. Zel’bst, and V. V. Belyaeva, Dokl. Chem., 455, No. 2, 167–170 (2014).
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Original Russian Text © 2016 I. V. Sterkhova, V. I. Smirnov, G. A. Kuznetsova, E. A. Zel’bst.
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Sterkhova, I.V., Smirnov, V.I., Kuznetsova, G.A. et al. Crystal and molecular structure of 1-(iodmethyl)- and 1-(iodpropyl)silatranes. J Struct Chem 57, 209–212 (2016). https://doi.org/10.1134/S0022476616010285
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DOI: https://doi.org/10.1134/S0022476616010285