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Studies on spectroscopic and crystal structure of dichloro carbonyl dipyridine triphenylarsine ruthenium(II) complex

  • Structure and Properties of Coordination Compounds
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Abstract

The title complex [Ru(Cl)2(CO)(py)2(AsPh3)], was synthesized and characterized. The molecular structure and crystal structures are determined by X-ray crystallography. The dihedral angle between the two cis-pyridine rings is 73.3(2)°, which shows that they are almost orthogonal to each other. The molecular structure is stabilized by inter-molecular and intra-molecular C–H…Cl interactions. The molecular structure is further stabilized by interactions between the aromatic rings.

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Author information

Authors and Affiliations

  1. Department of Chemistry, Avinashilingam University for Women, Coimbatore Tamilnadu, 641 043, India

    M. Gowri

  2. AS in Crystallography and Biophysics, University of Madras, Guindy Campus, Chennai Tamilnadu, 600 025, India

    T. Srinivasan & D. Velmurugan

Authors
  1. M. Gowri
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  2. T. Srinivasan
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  3. D. Velmurugan
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Corresponding author

Correspondence to T. Srinivasan.

Additional information

Original Russian Text © 2015 M. Gowri, T. Srinivasan, D. Velmurugan.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 8, pp. 1664-1667, December, 2015.

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Gowri, M., Srinivasan, T. & Velmurugan, D. Studies on spectroscopic and crystal structure of dichloro carbonyl dipyridine triphenylarsine ruthenium(II) complex. J Struct Chem 56, 1602–1605 (2015). https://doi.org/10.1134/S0022476615080223

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  • DOI: https://doi.org/10.1134/S0022476615080223

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