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Crystal structure and fluorescence of a 2D cadmium(II) coordination polymer based on flexible bis(2-methylbenzimidazole) and benzenedicarboxylate co-ligands

  • Structure and Properties of Coordination Compounds
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Abstract

A new coordination polymer, {[Cd(bbmb)(bdc)]} n (bbmb = 1,1′-(1,4-butanediyl)bis-(2-methylbenzimidazole), H2bdc = 1,3-benzenedicarboxylic acid) was synthesized under hydrothermal conditions. The complex was structurally characterized by single crystal X-ray diffraction analyses, infrared spectroscopy (IR), elemental analyses. The compound crystallizes in the monoclinic system, space group P21/c with a = 10.860(6) Å, b = 13.115(7) Å, c = 21.009(9) Å, β = 120.94(2)°, V = 2567(2) Å3, Z = 4, C28H26CdN4O4, M r = 594.93, D c = 1.540 g/cm3, μ = 0.893 mm–1. Each cadmium center is six coordinated with four O atoms from two bdc2– anions, and two N atoms of two bbmb ligands. The complex features a 4-connected 2D (4, 4) sheet with a point symbol {42.62}. Fluorescence properties of the title complex were investigated.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, Tangshan, Hebei Province, P. R. China

    H. H. Li, Y. Q. Zhao, G. Y. Li & G. H. Cui

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  1. H. H. Li
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  2. Y. Q. Zhao
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  3. G. Y. Li
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  4. G. H. Cui
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Correspondence to H. H. Li.

Additional information

Original Russian Text © 2015 H. H. Li, Y. Q. Zhao, G. Y. Li, G. H. Cui.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 8, pp. 1638- 1641, December, 2015.

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Li, H.H., Zhao, Y.Q., Li, G.Y. et al. Crystal structure and fluorescence of a 2D cadmium(II) coordination polymer based on flexible bis(2-methylbenzimidazole) and benzenedicarboxylate co-ligands. J Struct Chem 56, 1577–1580 (2015). https://doi.org/10.1134/S0022476615080181

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  • DOI: https://doi.org/10.1134/S0022476615080181

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