Abstract
[Ni(5,5′-dmbipy)2Cl2]·3H2O (1) complex was obtained from the reaction of NiCl2·6H2O with 5,5′-dimethyl-2,2′-bipyridine (5,5′-dmbipy) in a mixture of CH3OH/CH3CN. This complex was characterized by elemental analysis, IR, UV-Vis and luminescence spectroscopy, and its structure was determined by the single-crystal diffraction method. The Ni atom has a distorted octahedral coordination by four N atoms from two 5,5′-dmbipy ligands and two Cl– anions.
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14 December 2018
In the original publication the name of one of the authors had been misspelled. The correct name is T. Saemian.
28 December 2018
In the original publication the name of one of the authors had been misspelled. The correct name is T. Saemian.
References
E. Riedel, Anorganische Chemie, 6th ed., De Gruyter (2004).
B. Hipler, M. Döring, C. Dubs, H. Görls, T. Hübler, and E. Uhlig, Z. Anorg. Allg. Chem., 624, 1329–1335 (1998).
M. Ferbinteanu, F. Cimpoesu, M. Andruh, and F. D. Rochon, Polyhedron, 17, 3671–3679 (1998).
J. G. Malecki, B. Machura, and A. Switlicka, Struct. Chem., 22, 77–87 (2011).
B. H. Ye, X. M. Chen, G. Q. Xue, and L. N. Ji, J. Chem. Soc., Dalton Trans., 2827–2831 (1998).
A. Rujiwatra, S. Yimklan, and T. J. Prior, Polyhedron, 31, 345–351 (2012).
C. R. Pérez, L. P. A. Lorenzo, F. Lloret, and M. Julve, Inorg. Chim. Acta, 336, 131–136 (2002).
C. Janiak, S. Deblon, H. P. Wu, M. J. Kolm, P. Klüfers, H. Piotrowski, and P. Mayer, Eur. J. Inorg. Chem., 1507–1521 (1999).
F. Massicot, R. Schneider, Y. Fort, S. Illy-Cherrey, and O. Tillement, Tetrahedron, 57, 531–536 (2001).
T. J. J. Kinnunen, M. Haukka, T. T. Pakkanen, and T. A. Pakkanen, J. Organomet. Chem., 613, 257–262 (2000).
V. Amani, N. Safari, and H. R. Khavasi, Polyhedron, 26, 4257–4262 (2007).
V. Amani, N. Safari, H. R. Khavasi, and M. Akkurt, Polyhedron, 28, 3026–3030 (2009).
S. N. Ostad, S. M. Emadi, S. Tavajohi, V. Amani, and A. Abedi, Bull. Korean Chem. Soc., 33, No. 11, 3891–3894 (2012).
R. Alizadeh and V. Amani, Struct. Chem., 22, 1153–1163 (2011).
R. Alizadeh, V. Amani, A. A. Farshady, and H. R. Khavasi, J. Coord. Chem., 63, 2122–2131 (2010).
S. Karaca, M. Akkurt, N. Safari, V. Amani, O. Büyükgüngör, and A. Abedi, Acta Crystallogr., E65, m335–m336 (2009).
R. Ahmadi, K. Kalateh, and V. Amani, Acta Crystallogr., E66, m562 (2010).
A. Khalighi, R. Ahmadi, V. Amani, and H. R. Khavasi, Acta Crystallogr., E64, m1211–m1212 (2008).
K. Kalateh, R. Ahmadi, A. Ebadi, V. Amani, and H. R. Khavasi, Acta Crystallogr., E64, m1353–m1354 (2008).
Z. Ghiasi, V. Amani, P. Mirzaei, N. Safari, and A. Abedi, Aust. J. Chem., 66, 676–684 (2013).
T. Perera, P. Abhayawardhana, F. R. Fronczek, P. A. Marzilli, and L. G. Marzilli, Eur. J. Inorg. Chem., 618–627 (2012).
J. Phatchimkun, P. Kongsaeree, N. Suchaichit, and N. Chaichit, Acta Crystallogr., E65, m1020–m1021 (2009).
G. M. Sheldrick, SADABS, Bruker AXS, Madison, WI, USA (1998).
Bruker SMART and SAINT, Bruker AXS Inc., Madison, WI, USA (1998).
G. M. Sheldrick, Acta Crystallogr., A64, 112–122 (2008).
Mercury 1.4.1, Cambridge Crystallographic Data Center, Cambridge, UK (2001-2005).
V. Amani, N. Safari, and H. R. Khavasi, Polyhedron, 26, 4257–4262 (2007).
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compound, Part B: Application in Coordination, Organometallic and Bioinorganic Chemistry, John Wiley and Sons Inc., New York (2009).
V. Amani, N. Safari, H. R. Khavasi, and P. Mirzaei, Polyhedron, 26, 4908–4914 (2007).
V. Amani, N. Safari, B. Notash, and H. R. Khavasi, J. Coord. Chem., 62, 1939–1950 (2009).
C. M. Harris and E. D. McKenzie, J. Inorg. Nucl. Chem., 29, 1047–1068 (1967).
A. Abedi, N. Safari, V. Amani, and H. R. Khavasi, J. Coord. Chem., 65, 325–338 (2012).
A. Abedi, V. Amani, and N. Safari, Main Group Chem., 11, 223–233 (2012).
S. G. Liu, J. L. Zuo, Y. Z. Li, and X. Z. You, J. Mol. Struct., 705, 153–157 (2004).
C. K. Modi, D. H. Jani, H. S. Patel, and H. M. Pandya, Spectrochim. Acta, Part A, 75, 1321–1328 (2010).
F. G. Fontaine, Acta Crystallogr., E57, m270–m271 (2001).
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Original Russian Text © 2015 A. Abedi, E. Saemian, V. Amani.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 8, pp. 1606-1610, December, 2015.
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Abedi, A., Saemian, E. & Amani, V. Nickel(II) complex containing 5,5′-dimethyl-2,2′-bipyridine: Crystal structure and luminescent properties. J Struct Chem 56, 1545–1549 (2015). https://doi.org/10.1134/S0022476615080132
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DOI: https://doi.org/10.1134/S0022476615080132