Skip to main content
Log in

Nickel(II) complex containing 5,5′-dimethyl-2,2′-bipyridine: Crystal structure and luminescent properties

  • Structure and Properties of Coordination Compounds
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

An Erratum to this article was published on 28 December 2018

This article has been updated

Abstract

[Ni(5,5′-dmbipy)2Cl2]·3H2O (1) complex was obtained from the reaction of NiCl2·6H2O with 5,5′-dimethyl-2,2′-bipyridine (5,5′-dmbipy) in a mixture of CH3OH/CH3CN. This complex was characterized by elemental analysis, IR, UV-Vis and luminescence spectroscopy, and its structure was determined by the single-crystal diffraction method. The Ni atom has a distorted octahedral coordination by four N atoms from two 5,5′-dmbipy ligands and two Cl anions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

Change history

  • 14 December 2018

    In the original publication the name of one of the authors had been misspelled. The correct name is T. Saemian.

  • 28 December 2018

    In the original publication the name of one of the authors had been misspelled. The correct name is T. Saemian.

References

  1. E. Riedel, Anorganische Chemie, 6th ed., De Gruyter (2004).

    Google Scholar 

  2. B. Hipler, M. Döring, C. Dubs, H. Görls, T. Hübler, and E. Uhlig, Z. Anorg. Allg. Chem., 624, 1329–1335 (1998).

    Article  CAS  Google Scholar 

  3. M. Ferbinteanu, F. Cimpoesu, M. Andruh, and F. D. Rochon, Polyhedron, 17, 3671–3679 (1998).

    Article  CAS  Google Scholar 

  4. J. G. Malecki, B. Machura, and A. Switlicka, Struct. Chem., 22, 77–87 (2011).

    Article  CAS  Google Scholar 

  5. B. H. Ye, X. M. Chen, G. Q. Xue, and L. N. Ji, J. Chem. Soc., Dalton Trans., 2827–2831 (1998).

    Google Scholar 

  6. A. Rujiwatra, S. Yimklan, and T. J. Prior, Polyhedron, 31, 345–351 (2012).

    Article  CAS  Google Scholar 

  7. C. R. Pérez, L. P. A. Lorenzo, F. Lloret, and M. Julve, Inorg. Chim. Acta, 336, 131–136 (2002).

    Article  Google Scholar 

  8. C. Janiak, S. Deblon, H. P. Wu, M. J. Kolm, P. Klüfers, H. Piotrowski, and P. Mayer, Eur. J. Inorg. Chem., 1507–1521 (1999).

    Google Scholar 

  9. F. Massicot, R. Schneider, Y. Fort, S. Illy-Cherrey, and O. Tillement, Tetrahedron, 57, 531–536 (2001).

    Article  CAS  Google Scholar 

  10. T. J. J. Kinnunen, M. Haukka, T. T. Pakkanen, and T. A. Pakkanen, J. Organomet. Chem., 613, 257–262 (2000).

    Article  CAS  Google Scholar 

  11. V. Amani, N. Safari, and H. R. Khavasi, Polyhedron, 26, 4257–4262 (2007).

    Article  CAS  Google Scholar 

  12. V. Amani, N. Safari, H. R. Khavasi, and M. Akkurt, Polyhedron, 28, 3026–3030 (2009).

    Article  CAS  Google Scholar 

  13. S. N. Ostad, S. M. Emadi, S. Tavajohi, V. Amani, and A. Abedi, Bull. Korean Chem. Soc., 33, No. 11, 3891–3894 (2012).

    Article  CAS  Google Scholar 

  14. R. Alizadeh and V. Amani, Struct. Chem., 22, 1153–1163 (2011).

    Article  CAS  Google Scholar 

  15. R. Alizadeh, V. Amani, A. A. Farshady, and H. R. Khavasi, J. Coord. Chem., 63, 2122–2131 (2010).

    Article  CAS  Google Scholar 

  16. S. Karaca, M. Akkurt, N. Safari, V. Amani, O. Büyükgüngör, and A. Abedi, Acta Crystallogr., E65, m335–m336 (2009).

    Google Scholar 

  17. R. Ahmadi, K. Kalateh, and V. Amani, Acta Crystallogr., E66, m562 (2010).

    Google Scholar 

  18. A. Khalighi, R. Ahmadi, V. Amani, and H. R. Khavasi, Acta Crystallogr., E64, m1211–m1212 (2008).

    Google Scholar 

  19. K. Kalateh, R. Ahmadi, A. Ebadi, V. Amani, and H. R. Khavasi, Acta Crystallogr., E64, m1353–m1354 (2008).

    Google Scholar 

  20. Z. Ghiasi, V. Amani, P. Mirzaei, N. Safari, and A. Abedi, Aust. J. Chem., 66, 676–684 (2013).

    Article  CAS  Google Scholar 

  21. T. Perera, P. Abhayawardhana, F. R. Fronczek, P. A. Marzilli, and L. G. Marzilli, Eur. J. Inorg. Chem., 618–627 (2012).

    Google Scholar 

  22. J. Phatchimkun, P. Kongsaeree, N. Suchaichit, and N. Chaichit, Acta Crystallogr., E65, m1020–m1021 (2009).

    Google Scholar 

  23. G. M. Sheldrick, SADABS, Bruker AXS, Madison, WI, USA (1998).

    Google Scholar 

  24. Bruker SMART and SAINT, Bruker AXS Inc., Madison, WI, USA (1998).

  25. G. M. Sheldrick, Acta Crystallogr., A64, 112–122 (2008).

    Article  Google Scholar 

  26. Mercury 1.4.1, Cambridge Crystallographic Data Center, Cambridge, UK (2001-2005).

  27. V. Amani, N. Safari, and H. R. Khavasi, Polyhedron, 26, 4257–4262 (2007).

    Article  CAS  Google Scholar 

  28. K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compound, Part B: Application in Coordination, Organometallic and Bioinorganic Chemistry, John Wiley and Sons Inc., New York (2009).

    Google Scholar 

  29. V. Amani, N. Safari, H. R. Khavasi, and P. Mirzaei, Polyhedron, 26, 4908–4914 (2007).

    Article  CAS  Google Scholar 

  30. V. Amani, N. Safari, B. Notash, and H. R. Khavasi, J. Coord. Chem., 62, 1939–1950 (2009).

    Article  CAS  Google Scholar 

  31. C. M. Harris and E. D. McKenzie, J. Inorg. Nucl. Chem., 29, 1047–1068 (1967).

    Article  CAS  Google Scholar 

  32. A. Abedi, N. Safari, V. Amani, and H. R. Khavasi, J. Coord. Chem., 65, 325–338 (2012).

    Article  CAS  Google Scholar 

  33. A. Abedi, V. Amani, and N. Safari, Main Group Chem., 11, 223–233 (2012).

    CAS  Google Scholar 

  34. S. G. Liu, J. L. Zuo, Y. Z. Li, and X. Z. You, J. Mol. Struct., 705, 153–157 (2004).

    Article  CAS  Google Scholar 

  35. C. K. Modi, D. H. Jani, H. S. Patel, and H. M. Pandya, Spectrochim. Acta, Part A, 75, 1321–1328 (2010).

    Article  CAS  Google Scholar 

  36. F. G. Fontaine, Acta Crystallogr., E57, m270–m271 (2001).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Abedi.

Additional information

Original Russian Text © 2015 A. Abedi, E. Saemian, V. Amani.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 8, pp. 1606-1610, December, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Abedi, A., Saemian, E. & Amani, V. Nickel(II) complex containing 5,5′-dimethyl-2,2′-bipyridine: Crystal structure and luminescent properties. J Struct Chem 56, 1545–1549 (2015). https://doi.org/10.1134/S0022476615080132

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476615080132

Keywords

Navigation