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Crystal structure and magnetic properties of dinuclear iron(III) complex with ONNO-donor ligand

  • Structure and Properties of Coordination Compounds
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Abstract

A new dinuclear Fe(III) complex, [Fe(5-MeOL1)(OH)0.86(CH3O)0.14]2•2(CH3OH), [H2-5-MeOL1 = N,N′-bis(5-methoxy-2-hydroxybenzylidene)-2,2-dimethylpropane-1,3-diamine], 1 has been synthesized and characterized by single crystal structure analysis. The structure of 1 consists of two Fe(III) centers with one tetradentate schiff base ligand (N2O2) which are bridged by dihydroxo/dimethoxo groups to yield a Fe2O2 core. Complex 1 exhibits weak antiferromagnetic exchange interaction between Fe(III) ions with J = −0.21 cm–1.

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References

  1. a) K. P. Bryliakov and E. P. Talsi, Angew. Chem., Int. Ed., 43, 5228 (2004)

    Article  CAS  Google Scholar 

  2. T. Katsuki, Chem. Soc. Rev., 33, 437 (2004)

    Article  CAS  Google Scholar 

  3. A. Boettcher, M. W. Grinstaff, J. A. Labinger, and H. B. Gray, J. Mol. Catal. A: Chem., 113, 191 (1996)

    Article  CAS  Google Scholar 

  4. J.-E. Jee and C.-H. Kwak, Inorg. Chem. Commun., 33, 95 (2013).

    Article  CAS  Google Scholar 

  5. a) C. T. Brewer, G. Brewer, G. B. Jameson, P. Kamaras, L. May, and M. Rapta, J. Chem. Soc. Dalton Trans., 37 (1995)

    Google Scholar 

  6. M. M. Bhadbhade, and D. Srinivas, Polyhedron, 17, 2699 (1998).

    Article  CAS  Google Scholar 

  7. a) H. Fujii, T. Kurahashi, and T. Ogura, J. Inorg. Biochem., 96, 133 (2003)

    Article  Google Scholar 

  8. E. Y. Tshuva and S. J. Lippard, Chem. Rev., 104, 987 (2004)

    Article  CAS  Google Scholar 

  9. S. V. Kryatov, E. V. Rybak-Akimova, and S. Schindler, Chem. Rev., 105, 2175 (2005)

    Article  CAS  Google Scholar 

  10. K. S. Min, A. M. Arif, and J. S. Miller, Inorg. Chim. Acta, 360, 1854 (2007)

    Article  CAS  Google Scholar 

  11. T. Karimpour, E. Safaei, A. Wojtczak, and Z. Jaglicic, Inorg. Chim. Acta, 405, 309 (2013).

    Article  CAS  Google Scholar 

  12. a) S. M. Gorun and S. J. Lippard, Inorg. Chem., 30, 1625 (1991)

    Article  CAS  Google Scholar 

  13. E. Safaei, H. Sheykhi, T. Weyhermuller, and E. Bill, Inorg. Chim. Acta, 384, 69 (2012)

    Article  CAS  Google Scholar 

  14. H. Weihe and H. U. Gudel, J. Am. Chem. Soc., 119, 6539 (1997)

    Article  CAS  Google Scholar 

  15. H. J. Schugar, G. R. Rossman, and H. B. Gray, J. Am. Chem. Soc., 91, 4564 (1969)

    Article  CAS  Google Scholar 

  16. A. S. Attia and M. F. El-Shahat, Polyhedron, 26, 791 (2007).

    Article  CAS  Google Scholar 

  17. a) A. Karakas, E. Donmez, H. Kara, and A. Elmali, J. Nonlinear Opt. Phys. Mater., 16, 329 (2007)

    Article  CAS  Google Scholar 

  18. B. Chen, D. S. Contreras, Y. L. Clancy, and F. R. Fronczek, Acta Crystallogr., E60, m732 (2004)

    Google Scholar 

  19. L. Dyers, S. Y. Que, D. Van der Veer, and X. R. Bu, Inorg. Chim. Acta, 359, 197 (2006)

    Article  CAS  Google Scholar 

  20. Z. Chu, W. Huang, L. Wang, and S. Gou, Polyhedron, 27, 1079 (2008)

    Article  CAS  Google Scholar 

  21. M. Ahmadi, J. T. Mague, A. Akbari, and R. Takjoo, Polyhedron, 42, 128 (2012).

    Article  CAS  Google Scholar 

  22. a) Y. Yahsi, H. Kara, L. Sorace, and O. Buyukgungor, Inorg. Chem. Acta, 366, 191 (2011)

    Article  CAS  Google Scholar 

  23. Y. Yahsi, H. Kara, C. Kazak, A. Iakovenko, and L. Sorace, J. Optoelectron. Adv. Mater.-Symposia, 1, 566 (2009)

    Google Scholar 

  24. Z-L. You and H-L. Zhu, Acta Crystallogr., Sect. E, 60, m1046 (2004)

    Article  Google Scholar 

  25. M. Gerloch and F. E. Mabbs, J. Chem. Soc. A, 1900 (1967).

    Google Scholar 

  26. a) S. Jana, S. Chatterjee, and S. Chattopadhyay, Polyhedron, 48, 189 (2012)

    Article  CAS  Google Scholar 

  27. D. J. Darensbourg, C. G. Ortiz, and D. R. Billodeaux, Inorg. Chim. Acta, 357, 2143 (2004)

    Article  CAS  Google Scholar 

  28. G. Ilyashenko, M. Motevalli, and M. Watkinson, Tetrahedron: Asymmetry, 17, 1625 (2006)

    Article  CAS  Google Scholar 

  29. K. Oyaizu, E. L. Dewi, and E. Tsuchida, Inorg. Chim. Acta, 321, 205 (2001)

    Article  CAS  Google Scholar 

  30. A.-R. Li, H.-H. Wei, and L.-L. Gang, Inorg. Chim. Acta, 290, 51 (1999).

    Article  CAS  Google Scholar 

  31. a) S. Negoro, H. Asada, M. Fujiwara, and T. Matsushita, Inorg. Chem. Commun., 6, 357 (2003)

    Article  CAS  Google Scholar 

  32. R. Viswanathan, M. Palaniandavar, P. Prabakaran, and P. T. Muthiah, Inorg. Chem., 37, 3881 (1998)

    Article  CAS  Google Scholar 

  33. F. Banse, V. Balland, C. Philouze, E. Riviere, L. Tchertanova, and J.-J. Girerd, Inorg. Chim. Acta, 353, 223 (2003)

    Article  CAS  Google Scholar 

  34. R. Bikas, H. Hosseini-Monfared, G. Zoppellaro, R. Herchel, J. Tucek, A. M. Owczarzak, M. Kubicki, and R. Zboril, Dalton Trans., 42, 2803 (2013).

    Article  CAS  Google Scholar 

  35. a) Q. Liu, S. Pan, and D. Wang, Acta Crystallogr., E65, m305 (2009)

    Google Scholar 

  36. K. Matsumoto, H. Egami, T. Oguma, and T. Katsuki, Chem. Commun., 48, 5823 (2012)

    Article  CAS  Google Scholar 

  37. L. Borer, L. Thalken, C. Ceccarelli, M. Glick, J. H. Zhang, and W. M. Reiff, Inorg. Chem., 22, 1719 (1983).

    Article  CAS  Google Scholar 

  38. S. L. Jain, P. Bhattacharyya, H. L. Milton, A. M. Z. Slawin, and J. D. Woollins, Inorg. Chem. Commun., 7, 423 (2004).

    Article  CAS  Google Scholar 

  39. O. Kahn, Molecular Magnetism, VCH, New York (1993).

    Google Scholar 

  40. Bruker-AXS SAINT V7.60A (2008).

  41. G. M. Sheldrick, SADABS V2008/1, University of Göttingen, Germany (2008).

    Google Scholar 

  42. G. Sheldrick, Acta Crystallogr., Sect. A: Found. Crystallogr., A64, 112 (2008).

    Article  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Faculty of Science and Art, Balikesir University, Balikesir, Turkey

    B. Safak, Y. Yahsi, E. Gungor & H. Kara

  2. Department of Physics, Faculty of Science, Mugla Sitki Koçman University, Mugla, Turkey

    H. Kara

Authors
  1. B. Safak
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  2. Y. Yahsi
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  3. E. Gungor
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  4. H. Kara
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Corresponding author

Correspondence to E. Gungor.

Additional information

Original Russian Text © 2015 B. Safak, Y. Yahsi, E. Gungor, H. Kara.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 8, pp. 1588-1593, December, 2015.

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Safak, B., Yahsi, Y., Gungor, E. et al. Crystal structure and magnetic properties of dinuclear iron(III) complex with ONNO-donor ligand. J Struct Chem 56, 1527–1532 (2015). https://doi.org/10.1134/S0022476615080107

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  • DOI: https://doi.org/10.1134/S0022476615080107

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