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Crystal structure of trans-[ReO2(3,5-lut)4]I3

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Abstract

The trans-[ReO2(3,5-lut)4]I3 complex (trans-dioxotetra(3,5-lutidine)rhenium(V) triiodide) is obtained by the reaction of ReI3 with 3,5-lutidine (3,5-lut) in acetonitrile. The structure is triclinic, space group P \(\bar 1\), a = 8.5224(9) Å, b = 8.9607(9) Å, c = 12.6271(12) Å, α = 76.987(3)°, β = 73.932(3)°, γ = 65.500(3)°, V = 836.44(15) Å3, Z = 1, d calc = 2.040 g/cm3. Re atoms have an octahedral coordination environment formed by N atoms of 3,5-lutidine molecules and О atoms in the trans-position.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    A. V. Ermolaev, M. A. Shestopalov, N. V. Kuratieva & Yu. V. Mironov

  2. Novosibirsk National Research State University, Novosibirsk, Russia

    M. A. Shestopalov, N. V. Kuratieva & Yu. V. Mironov

Authors
  1. A. V. Ermolaev
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  2. M. A. Shestopalov
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  3. N. V. Kuratieva
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  4. Yu. V. Mironov
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Correspondence to A. V. Ermolaev.

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Original Russian Text © 2015 A. V. Ermolaev, M. A. Shestopalov, N. V. Kuratieva, Yu. V. Mironov.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 56, No. 7, pp. 1500-1502, November-December, 2015.

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Ermolaev, A.V., Shestopalov, M.A., Kuratieva, N.V. et al. Crystal structure of trans-[ReO2(3,5-lut)4]I3 . J Struct Chem 56, 1446–1448 (2015). https://doi.org/10.1134/S002247661507032X

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  • DOI: https://doi.org/10.1134/S002247661507032X

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