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Structural characterisation and photoluminescence of a pyridine–diimine compound

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Abstract

A pyridine–diimine compound N,N′-[pyridine-2,6-diyldi(E)methylylidene]bis(4-chloroaniline) is synthesised by a Schiff base condensation of 2,6-diformylpyridine with 4-chloroaniline in methanol and characterised by spectroscopic and analytical techniques. The molecular structure of the compound is determined by the single crystal X-ray diffraction study. The compound crystallizes in the monoclinic crystal system, I2/c space group with unit cell parameters a = 7.0843(12) Å, b = 6.1909(11) Å, c = 36.262(6) Å, β = 91.576(3)°, V = 1589.8(5) Å3 and Z = 4. There is an intermolecular hydrogen bonding in the molecule resulting in a 1D hydrogen bonding chain and these hydrogen bonding chains are linked by Cl…HC(aromatic) interactions forming a 2D network. Crystal packing of the compound is determined by Cl…HC and π–π interactions. In the fluorescence emission spectra in CH3CN, DMF, DMSO and EtOH, the compound shows only one emission maximum.

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Authors and Affiliations

  1. Chemistry Department, Kahramanmaras Sütçü Imam University, Kahramanmaraş, Turkey

    M. Köse, G. Ceyhan, S. A. Güngör & S. Purtaş

  2. Chemistry Department, Loughborough University, Leicestershire, UK

    V. McKee

Authors
  1. M. Köse
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  2. G. Ceyhan
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  3. S. A. Güngör
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  4. S. Purtaş
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  5. V. McKee
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Corresponding author

Correspondence to M. Köse.

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Original Russian Text © 2015 M. Köse, G. Ceyhan, S. A. Güngör, S. Purtaş, V. McKee.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 7, pp. 1415-1421, November-December, 2015.

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Köse, M., Ceyhan, G., Güngör, S.A. et al. Structural characterisation and photoluminescence of a pyridine–diimine compound. J Struct Chem 56, 1353–1359 (2015). https://doi.org/10.1134/S0022476615070161

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  • DOI: https://doi.org/10.1134/S0022476615070161

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