Skip to main content
SpringerLink
Log in

Сrystal structure and magnetic property of a new two-dimensional coordination polymer constructed by 1,4-bis(1,2,4-triazol-1-ylmethyl)-benzene and 4,4′-sulfonyldibenzoic acid

  • Brief Communications
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

A two-dimensional Ni(II) complex {[Ni(BTX)(SDBA)(H2O)]•0.29H2O} n (1) (BTX = 1,4-bis(1,2,4-triazol-1-ylmethyl)-benzene, H2SDBA = 4,4′-sulfonyldibenzoic acid) is synthesized and characterized using single crystal X-ray diffraction, IR spectroscopy, and elemental analysis. The single crystal X-ray diffraction analysis reveals that complex 1 is a two-dimensional polymer containing 28-membered rings based on the rhomboid subunit [Ni2(C14H8O6S)2] with a Ni–Ni separation of 12.923 Å. The thermal stability and magnetic property of the title complex are briefly investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. S. Kitagawa, R. Kitaura, and S. Noro, Angew. Chem., Int. Ed., 43, 2334–2375 (2004).

    Article  CAS  Google Scholar 

  2. G. Ferey, C. Mellot-Draznieks, C. Serre, et al., Acc. Chem. Res., 38, 217–225 (2005).

    Article  CAS  Google Scholar 

  3. S. Roy, G. Mahata, and K. Biradha, Cryst. Growth Des., 9, 5006–5008 (2009).

    Article  CAS  Google Scholar 

  4. Y. B. Zhang, W. X. Zhang, F. Y. Feng, et al., Angew. Chem., Int. Ed., 48, 5287–5290 (2009).

    Article  CAS  Google Scholar 

  5. H. L. Jiang, B. Liu, and Q. Xu, Cryst. Growth Des., 10, 806–811 (2010).

    Article  CAS  Google Scholar 

  6. W.-Q. Kan, B. Liu, J. Yang, et al., Cryst. Growth Des., 12, 2288–2298 (2012).

    Article  CAS  Google Scholar 

  7. Y.-Y. Liu, J. Li, J.-F. Ma, et al., CrystEngComm, 14, 169–177 (2012).

    Article  CAS  Google Scholar 

  8. W.-J. Zhuang, C.-Y. Sun, and L.-P. Jin, Polyhedron, 26, 1123–1132 (2007).

    Article  CAS  Google Scholar 

  9. F.-Y. Lian, F.-L. Jiang, D.-Q. Yuan, et al., CrystEngComm, 10, 905–914 (2008).

    Article  CAS  Google Scholar 

  10. D. Xiao, R. Yuan, Y. Chai, et al., Eur. J. Inorg. Chem., 2610–2615 (2008).

    Google Scholar 

  11. X.-L. Chen, L. Gou, H.-M. Hu, et al., Eur. J. Inorg. Chem., 239–250 (2008).

    Google Scholar 

  12. J.-Q. Liu, Y.-N. Zhang, Y.-Y. Wang, et al., Dalton Trans., 5365–5378 (2009).

    Google Scholar 

  13. N. Li, L. Chen, F. Lian, et al., Inorg. Chim. Acta, 363, 3291–3301 (2010).

    Article  CAS  Google Scholar 

  14. X. Meng, Y. Liu, Y. Song, et al., Inorg Chim Acta, 358, 3024–3032 (2005).

    Article  CAS  Google Scholar 

  15. Y.-F. Peng, H.-Y. Ge, B.-Z. Li, et al., Cryst. Growth Des., 6, 994–998 (2006).

    Article  CAS  Google Scholar 

  16. J.-L. Du, T.-L. Hu, S.-M. Zhang, et al., CrystEngComm, 10, 1866–1874 (2008).

    Article  CAS  Google Scholar 

  17. J. Hu, J. Li, J. Zhao, et al., Inorg. Chim. Acta, 362, 5023–5030 (2009).

    Article  CAS  Google Scholar 

  18. S. Huang, X. Li, X. Shi, et al., J. Mater. Chem., 20, 5695–5699 (2010).

    Article  CAS  Google Scholar 

  19. S.-Y. Zhang, W. Shi, Y. Lan, et al., Chem. Commun., 47, 2859–2861 (2011).

    Article  CAS  Google Scholar 

  20. O. Kahn, J. Molecular Magnetism, VCH Publishers (1993).

    Google Scholar 

  21. G. M. Sheldrick, J. SADABS, An Empirical Absorption Correction Program, Bruker Analytical X-ray Systems, Madison, WI (1996).

    Google Scholar 

  22. G. M. Sheldrick, J. SHELXL-97, Program for Refinement Of Crystal Structures, University of Göttingen, Germany (1997).

    Google Scholar 

  23. S. M. Krishnan, R. M. Supkowski, and R. L. LaDuca, Cryst. Growth Des., 9, 358–363 (2009).

    Article  CAS  Google Scholar 

  24. S.-S. Chen, Z.-H. Chen, J. Fan, et al., Cryst. Growth Des., 12, 2315–2326 (2012).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Department of Chemistry, Yancheng Teachers University, Yancheng, Jiangsu, 224002, P. R. China

    X. J. Xu

Authors
  1. X. J. Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to X. J. Xu.

Additional information

Original Russian Text © 2015 X. J. Xu.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 5, pp. 1066–1070, September–October, 2015.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Xu, X.J. Сrystal structure and magnetic property of a new two-dimensional coordination polymer constructed by 1,4-bis(1,2,4-triazol-1-ylmethyl)-benzene and 4,4′-sulfonyldibenzoic acid. J Struct Chem 56, 1008–1012 (2015). https://doi.org/10.1134/S0022476615050285

Download citation

  • Received:

  • Revised:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476615050285

Keywords

Search

Navigation