Abstract
In this paper, we report the preparation of a four-coordinated copper(I) thiosemicarbazone complex [CuI(PPh3)(catsc)] from the reaction of PPh3 and catsc (3-phenylpropenalthiosemicarbazone) with CuI. The synthesized complex is characterized by elemental analyses (CHNS) and FT-IR spectroscopy. The crystal structure of [CuI(PPh3)(catsc)] is investigated by single crystal X-ray diffraction. The catsc coordinates to the copper(I) ion as a bidentate ligand via the N and S atoms. The complex has a distorted tetrahedral coordination geometry.
This is a preview of subscription content, log in via an institution to check access.
References
A. M. Palve, P. V. Joshi, V. Puranik, and S. S. Garje, Polyhedron, 61, 195–201 (2013).
R. N. Prabhu and R. Ramesh, Tetrahedron Lett., 54, 1120–1124 (2013).
A. I. Matesanz and P. Souza, Inorg. Chem. Commun., 27, 5–8 (2013).
D. Pandiarajan, R. Ramesh, Y. Liu, and R. Suresh, Inorg. Chem. Commun., 33, 33–37 (2013).
M. Joseph, M. Kuriakose, M. R. Prathapachandra, K. E. Suresh, A. Kishore, and S. G. Bhat, Polyhedron, 25, 61–70 (2006).
S. Mathan Kumar, K. Dhahagani, J. Rajesh, K. Nehru, J. Annaraj, G. Chakkaravaethi, and G. Rajagopal, Polyhedron, 59, 58–68 (2013).
T. S. Lobana, A Rekha, and R. J. Butcher, Trans. Met. Chem., 29, 291–295 (2004).
T. S. Lobana, R. Sharma, G. Hundal, A. Castineiras, and R. J. Butcher, Polyhedron, 47, 134–142 (2012).
T. S. Lobana, A Rekha, R. J. Butcher, A. Castineiras, E. Bermejo, and P. V. Bharatam, Inorg. Chem., 45, 1535–1542 (2006).
T. S. Lobana, S. Khanna, G. Hundal, R. J. Butcher, and A. Castineiras, Polyhedron, 28, 3899–3906 (2009).
T. S. Lobana, P. Kumari, and R. J. Butcher, Inorg. Chem. Commun., 11, 11–14 (2008).
M. Hakimi, H. Vahedi, M. Rezvaninezhad, E. Schuh, and F. Mohr, J. Sulf. Chem., 32, 55–61 (2011).
Y. M. Chumakov, N. M. Samus, G. Bocelli, K. Y. Suponitskii, V. I. Taspkov, and A. P. Gulya, Russ. J. Coord. Chem., 32, 14–20 (2006).
L. Palatinus and G. Chapuis, J. Appl. Crystallogr., 40, 786 (2007).
V. Petricek, M. Dusek, and L. Palatinus, Z. Kristallogr., 229, 345–352 (2014).
L. J. Farrugia, J. Appl. Crystallogr., 30, 656 (1997).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2015 E. Shahsavani, N. Feizi, V. Eigner, M. Dusek, A. D. Khalaji.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 5, pp. 1061–1065, September–October, 2015.
Rights and permissions
About this article
Cite this article
Shahsavani, E., Feizi, N., Eigner, V. et al. Crystal structure of copper(I) thiosemicarbazone complex [CuI(PPh3)(catsc)]. J Struct Chem 56, 1003–1007 (2015). https://doi.org/10.1134/S0022476615050273
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476615050273