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Solvothermal syntheses, crystal structure, and photoluminescent properties of two Cu(I) coordination polymers constructed by bisimidazole ligands

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Abstract

Two Cu(I) coordination polymers {[Cu2(bibp)2]·bdc·3H2O} n (1) and {[Cu3(bib)3]·btc·5H2O} n (2), where bibp = 4,4′-bis(1-imidazol-1-yl)biphenyl, H2bdc = terephthalic acid, bib = 1,4-bis(1-imidazol-1-yl)benzene, H3btc = benzene-1,3,5-tricarboxylic acid, are synthesized under solvothermal conditions and characterized structurally. Complex 1 crystallizes in the triclinic form with the space group P-1, and Cu(1) is two-coordinated by two N atoms of bibp, Cu(2) is three coordinated from two N atoms of bibp and one water molecule. Complex 2 crystallizes in the triclinic form with the space group P-1; the copper ions are monovalent and two-coordinated by two N atoms of bib. The bdc and btc ligands are not coordinated with Cu ions, but play important roles in the generation of a 3D supramolecular structure of complexes 1 and 2 via weak interactions respectively.

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Authors and Affiliations

  1. School of Chemistry and Life Science, Anshan Normal University, Anshan, P. R. China

    K. -H. Wang, D. -L. Wang, J. Bai, Y. Liu, G. Xin, T. -C. Li & D. -Y. Hou

  2. Laboratory of Coordination Chemistry, Shenyang University of Chemical Technology, Shenyang, P. R. China

    M. -C. Zhu & E. -J Gao

Authors
  1. K. -H. Wang
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  2. M. -C. Zhu
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  3. D. -L. Wang
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  4. J. Bai
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  5. Y. Liu
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  6. G. Xin
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  7. T. -C. Li
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  8. D. -Y. Hou
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  9. E. -J Gao
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Correspondence to K. -H. Wang.

Additional information

Original Russian Text © 2015 K.-H. Wang, M.-C. Zhu, D.-L. Wang, J. Bai, Y. Liu, G. Xin, T.-C. Li, D.-Y. Hou, E.-J Gao.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 1, pp. 198–203, January–February, 2015.

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Wang, K.H., Zhu, M.C., Wang, D.L. et al. Solvothermal syntheses, crystal structure, and photoluminescent properties of two Cu(I) coordination polymers constructed by bisimidazole ligands. J Struct Chem 56, 191–196 (2015). https://doi.org/10.1134/S002247661501028X

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  • DOI: https://doi.org/10.1134/S002247661501028X

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