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Crystal structure of the copper(I) complex Cu(py-Clan)(PPh3)I

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Abstract

A mixed ligand copper(I) Schiff base complex [Cu(py-Clan)(PPh3)I], where py-Clan = = 4-chlorophenylpyridine-2-ylmethyleneamine, is synthesized and structurally characterized by single crystal X-ray crystallography. In this complex, the copper(I) ion is in a distorted four-coordinate tetrahedral geometry. The Schiff base py-Clan ligand acts as a chelating ligand and coordinates to the copper center via two nitrogen atoms. The [Cu(py-Clan)(PPh3)I] complex crystallizes in the monoclinic space group P21/c with unit cell parameters: a = 10.3339(12) Å, b = 34.524 Å, c = 8.3940 Å, β = 114.759(8)°, V = 2719.4(5) Å3 and Z = 4.

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Authors and Affiliations

  1. Department of Chemistry, Golestan University, Faculty of Science, Gorgan, Iran

    A. D. Khalaji

  2. Department of Chemistry, Shahrood University of Technology, Shahrood, Iran

    K. Jafari

  3. Institute of Physics of the ASCR, v.v.i., Prague, Czech Republic

    K. Fejfarova & M. Dusek

Authors
  1. A. D. Khalaji
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  2. K. Jafari
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  3. K. Fejfarova
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  4. M. Dusek
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Corresponding author

Correspondence to A. D. Khalaji.

Additional information

Original Russian Text © 2015 A. D. Khalaji, K. Jafari, K. Fejfarova, M. Dusek.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 56, No. 1, pp. 183–186, January–February, 2015.

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Khalaji, A.D., Jafari, K., Fejfarova, K. et al. Crystal structure of the copper(I) complex Cu(py-Clan)(PPh3)I. J Struct Chem 56, 175–178 (2015). https://doi.org/10.1134/S0022476615010230

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  • DOI: https://doi.org/10.1134/S0022476615010230

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