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Crystal structural and fluorescence properties of a two-dimensional cobaltous coordination polymer containing bis(benzimidazole) ligand

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Abstract

A new 2D coordination polymer {[Co(IPA)(L)]·0.25H2O} n (L = 1,4-bis(5,6-dimethyl-benzimidazolyl)-2-butene, H2IPA = 5-hydroxyisophthalic acid) is hydrothermally synthesized and characterized by elemental analysis, IR, and single crystal X-ray diffraction. The structure analysis indicates that the compound belongs to the orthorhombic system, space group Pnma, a = 17.5256(2) Å, b = 15.2074(2) Å, c = 9.7633(1) Å and Z = 4. The complex possesses a 2D (4, 4) network structure and the adjacent layers are further assembled into a 3D supramolecular framework via intermolecular O-H⋯O hydrogen bond interactions. The luminescent properties of the compound and free ligand L are investigated in the solid state.

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Authors and Affiliations

  1. College of Chemical Engineering, Hebei United University, Tangshan, Hebei Province, P. R. China

    C. L. Ming, X. Du, L. Qin & G. H. Cui

Authors
  1. C. L. Ming
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  2. X. Du
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  3. L. Qin
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  4. G. H. Cui
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Corresponding author

Correspondence to C. L. Ming.

Additional information

Original Russian Text © 2014 C. L. Ming, X. Du, L. Qin, G. H. Cui.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 5, pp. 973–977, September–October, 2014.

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Ming, C.L., Du, X., Qin, L. et al. Crystal structural and fluorescence properties of a two-dimensional cobaltous coordination polymer containing bis(benzimidazole) ligand. J Struct Chem 55, 927–931 (2014). https://doi.org/10.1134/S0022476614050205

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  • DOI: https://doi.org/10.1134/S0022476614050205

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