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Structure of diethylenetriammonium tetrabromoaurates(III)

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Abstract

In HAuBr4 interaction with diethylenetriamine in HBr, new complexes (DienH3)2[AuBr4]3Br3·4H2O (I) and (DienH3)[AuBr4]3·H2O (II) (where DienH 3+3 is protonated diethylenetriamine) are obtained, which are characterized by elemental analysis, single crystal X-ray diffraction, thermogravimetry, and IR spectroscopy. For I, the crystals are triclinic, crystallize in the space group P-1, a = 7.9717(3) Å, b = 11.0178(4) Å, c = 12.6765(5) Å, α = 75.960(1)°, β = 75.031(1)°, γ = 75.681(1)°, V = 1023.02(7) Å3, Z = 2. For II, the crystals are orthorhombic, crystallize in the space group Pnma, unit cell parameters are as follows: a = 4.2981(8) Å, b = 15.394(3) Å, c = 13.402(3) Å, V = 886.7(3) Å3, Z = 4.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    E. V. Makotchenko, I. A. Baidina & I. V. Korol’kov

  2. Novosibirsk State University, Novosibirsk, Russia

    E. V. Makotchenko

Authors
  1. E. V. Makotchenko
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  2. I. A. Baidina
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  3. I. V. Korol’kov
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Correspondence to E. V. Makotchenko.

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Original Russian Text © 2014 E. V. Makotchenko, I. A. Baidina, I. V. Korol’kov.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 5, pp. 933–940, September–October, 2014.

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Makotchenko, E.V., Baidina, I.A. & Korol’kov, I.V. Structure of diethylenetriammonium tetrabromoaurates(III). J Struct Chem 55, 887–894 (2014). https://doi.org/10.1134/S0022476614050138

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  • DOI: https://doi.org/10.1134/S0022476614050138

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