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Features of the composition and structural transformations of manganese minerals of the lake Bol’shoe Miassovo (South Ural)

  • Proceedings of the Conference “Methods for Studying the Composition and Structure of Functional Materials,” October 21–25, 2013, Novosibirsk
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Abstract

The mineral and microelement composition of natural manganese minerals from iron-manganese concretions of the Bol’shoe Miassovo lake (South Ural) is investigated. The structural transformations of the samples under the effect of different temperatures are studied. Apart from layered 9.6 Å and 7.2 Å structures of manganese minerals the lake samples often contain various manganese-containing carbonates. For carbonate minerals by IR spectroscopy the dependence of the wavenumbers of ν2 and ν4 vibrations of the CO3 group on the mineral composition is analyzed. The composition of macro- and microelements of iron-manganese concretions of Bol’shoe Miassovo lake varies in wide ranges not only in different samples, but also in different parts of the same sample. An analysis of the microstructure of lake manganese concretions revealed their biomorphic nature that is exhibited in globe-shaped to filament organic bacterial forms.

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References

  1. A. I. Vasil’eva, L. M. Gramm-Osipov, and T. N. Grigor’eva, Proc. of the Institute of Geology and Geophysics [in Russian], Siberian Branch, Russian Academy of Sciences, Vyp. 729, Nauka, Novosibirsk (1990).

    Google Scholar 

  2. G. N. Baturin, Geochemistry of Iron-Manganese Oceanic Concretions [in Russian], Nauka, Moscow (1986).

    Google Scholar 

  3. Supriya Roy, Manganese Deposits, Academ Press, London-New York-Toronto-Sydney-San Francisco (1986).

    Google Scholar 

  4. T. N. Grigorieva, G. Dubinina, T. N. Moroz, and N. A. Palchik, Tikhookean. Geol., 17, No. 4, 59 (1998).

    Google Scholar 

  5. N. A. Palchik, T. N. Grigorieva, and T. N. Moroz, Zh. Neorg. Khim., 58, No. 2, 138 (2013).

    CAS  Google Scholar 

  6. P. M. Valizer, E. P. Shcherbakova, T. N. Moroz, A. S. Nikandrov, and S. N. Nikandrov, Vest. Inst. Geol., Komi SC, Ural Branch, Russian Academy of Sciences, No. 12, 17 (2012).

    Google Scholar 

  7. Yu. B. Kornilov and T. Yu. Veretennikova, Proc. of the 3rd Regional Meeting “Mineralogy of Ural” [in Russian], Miass, 1, 150 (1998).

    Google Scholar 

  8. V. B. Baryshev, G. N. Kulipanov, A. N. Skrinsky, in: Handbook on Synchrotron Radiation, G. S. Brown and D. E. Moncton(eds.), Elsevier, Amsterdam (1991), 3, 641–688.

  9. F. V. Chukhrov, A. I. Gorshkov, and V. A. Drits, Hypergenic Manganese Oxides [in Russian], Nauka, Moscow (1989).

    Google Scholar 

  10. T. N. Grigor’eva, A. V. Vasil’eva, and T. A. Korneva, in:Minerals and Methods of Their Investigation, N. A. Poroshina (ed.) [in Russian], Izd. NGPI, Novosibirsk (1989), pp. 60–67.

  11. S. V. Gevorkyan, V. S. Lyashenko, and E. A. Yanchuk, Diagnostics of Manganese Minerals [in Russian], Naukova dumka, Kiev (1991).

    Google Scholar 

  12. R. M. Potter and G. R. Rossman, Am. Miner., 64, 1199 (1979).

    CAS  Google Scholar 

  13. W. B. White, in: The Infrared Spectra of Minerals, V. C. Farmer (ed.), Mineralogy Society, London (1974) pp. 227–284.

  14. M. E. Bottcher, P. L. Gehlken, and R. Usdowski, Contrib. Mineral. Petrolog., 109, 304 (1992).

    Article  Google Scholar 

  15. Y. Dauphin, Applied Spectroscopy, 53, No. 2, 184 (1999).

    Article  CAS  Google Scholar 

  16. J. V. Dubrawski, A. L. Channon, and S. Warne, Am. Miner., 74, 187 (1989).

    CAS  Google Scholar 

  17. C. K. Huang and P. F. Kerr, Am. Miner., 45, 311 (1960).

    CAS  Google Scholar 

  18. V. C. Farmer and S. S. J. Warne, Am. Miner., 63, 779 (1978).

    CAS  Google Scholar 

  19. A. N. Derkachev, B. V. Baranov, B. Ya. Karp, E. N. Sukhoveev, T. N. Grigor’eva, N. A. Pal’chik, and T. N. Moroz, Dokl. Earth Sci., 427, No. 5, 728 (2009).

    Article  CAS  Google Scholar 

  20. N. A. Pal’chik, T. N. Grigor’eva, T. N. Moroz, A. N. Derkachev, and L. G. Gilinskaya, Fundamental’nye Problemy Sovremennogo Materialovedeniya, 6, No. 4, 73 (2009).

    Google Scholar 

  21. T. N. Moroz, N. A. Palchik, A. V. Dar’in, and T. N. Grigorieva, Izv. Ross. Akad. Nauk, Ser. Fiz., 77, No. 2, 195 (2013).

    CAS  Google Scholar 

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Authors and Affiliations

  1. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    N. A. Palchik, T. N. Moroz & T. N. Grigorieva

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  1. N. A. Palchik
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  2. T. N. Moroz
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  3. T. N. Grigorieva
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Correspondence to N. A. Palchik.

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Original Russian Text © 2014 N. A. Palchik, T. N. Moroz, T. N. Grigorieva.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 4, pp. 798–804, July–August, 2014.

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Palchik, N.A., Moroz, T.N. & Grigorieva, T.N. Features of the composition and structural transformations of manganese minerals of the lake Bol’shoe Miassovo (South Ural). J Struct Chem 55, 764–770 (2014). https://doi.org/10.1134/S0022476614040271

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  • DOI: https://doi.org/10.1134/S0022476614040271

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