Abstract
The hydrothermal reaction of CuCN and bpy in the presence of an octahedral cluster complex K2.75Cs1.25[Re6Se8(CN)4(OH)2]·H2O affords a cyanide-bridged chain coordination polymer [CuCN(bpy)] n (bpy — 2,2′-bipyridyl) (1). The structure is monoclinic, space group C2/c, a = 22.848(2) Å, b = 7.7182(8) Å, c = 14.4331(13) Å, β = 127.805(2)°, V = 2010.9(3) Å3, Z = 8, d x = 1.623 g/cm3. Copper atoms have a tetrahedral coordination environment formed by N atoms of the bpy molecule as well as N and C atoms of ambidentate bridging CN ligands.
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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 4, pp. 765–767, July–August, 2014.
Original Russian Text © 2014 A. V. Ermolaev, A. I. Smolentsev, Yu. V. Mironov.
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Ermolaev, A.V., Smolentsev, A.I. & Mironov, Y.V. Crystal structure of a new modification of the cyanide-bridged copper(I) coordination compound [CuCN(bpy)] n . J Struct Chem 55, 731–733 (2014). https://doi.org/10.1134/S0022476614040210
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DOI: https://doi.org/10.1134/S0022476614040210