Abstract
Polyerther-linked mercury(II) carbene complexes are synthesized by the reaction of carbene precursores with mercury(II) acetate. The binuclear carbene complexes with the chloride ion linkage are easily prepared by the reaction of mononuclear mercury carbene complexes with tetrabutylammoium chloride. The crystal structures reveal that the fluorescence of mercury complexes are related to the coordination mode of the ligands.
Similar content being viewed by others
References
D. Bourissou, F. P. Guerret, and G. Bertrand, Chem. Rev., 100, 39 (2000).
W. A. Herrmann and C. Köcher, Angew. Chem., Int. Ed. Eng., 36, 2162 (1997).
P. L. Arnold, A. C. Scarisbrick, and C. Wilson, Chem. Commun., 2340 (2001).
R. E. Douthwaite, M. L. H. Green, P. J. Silcock, and P. T. Gomes, Organometallics, 20, 2611 (2001).
W. A. Herrmann, M. Elison, J. Fischer, C. Kocher, and G. R. J. Artus, Angew. Chem., Int. Ed. Eng., 34, 2371 (1995).
E. Peris, J. A. Loch, J. Mata, and R. H. Crabtree, Chem. Commun., 201 (2001).
A. J. Arduengo and R. L. Harlow, J. Am. Chem. Soc., 113, 361 (1992).
W. A. Herrmann, Angew. Chem., Int. Ed., 41, 1291 (2002).
R. W. Alder, M. E. Blake, and M. J. Quayle, Chem. Commun., 241 (1999).
P. G. Bazinet, P. A. Yap, and D. S. Richeson, J. Am. Chem. Soc., 125, 13314 (2003).
R. Weiss, S. Reichel, M. Handke, and F. Hampel, Angew. Chem., Int. Ed., 37, 344 (1998).
J. C. C. Chen and I. J. B. Lin, J. Chem. Soc., Dalton Trans., 839 (2000).
U. J. Scheele, S. Dechert, and F. Meyer, Inorg. Chim. Acta, 359, 4891 (2006).
K.-M. Lee, J. C. C. Chen, and I. J. B. Lin, J. Organomet. Chem., 617/618, 364 (2001).
Y.-S. Liu, X.-J. Wan, and F.-B. Xu, Organometallics, 28, 5590 (2009).
T. Fahlbusch, M. Frank, G. Maas, and J. Schatz, Organometallics, 28, 6183 (2009).
Q.-X. Liu, L.-N. Yin, X.-M. Wu, J.-C. Feng, J.-H. Guo, and H.-B. Song, Polyhedron, 27, 87 (2008).
J. D. Holbrey, A. E. Visser, S. K. Spear, W. M. Reichert, R. P. Swatloski, G. A. Broker, and R. D. Rogers, Green Chemistry, 5, 129 (2003).
J.-W. Wang, H.-B. Song, Q.-S. Li, F.-B. Xu, and Z.-Z. Zhang, Inorg. Chim. Acta, 358, 3653 (2005).
J.-W. Wang, Q.-S. Li, F.-B. Xu, H.-B. Song, and Z.-Z. Zhang, Eur. J. Org. Chem., 1310 (2006).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2014 J.-W. Wang, M.-C. Zhang.
The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 4, pp. 737–742, July–August, 2014.
Rights and permissions
About this article
Cite this article
Wang, J.W., Zhang, M.C. Fluorescence and crystal structures of new mercury(II) macrocyclic N-heterocyclic carbene complexes with ether chains. J Struct Chem 55, 703–708 (2014). https://doi.org/10.1134/S0022476614040167
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476614040167