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Unusual layer structure in an ion-paired compound containing tetra(isothiocyanate) cobalt(II) dianion and 4-nitrobenzylpyridinium: Crystal structure and magnetic properties

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Abstract

A new ion-paired compound [4NO2BzPy]2[Co(NCS)4] (1) ([4NO2BzPy]+ = 1-(4′-nitrobenzyl)pyridinium, NCS− = isothiocyanate) is synthesized and characterized by elemental analysis, IR and UV-Vis spectra, ESI-MS and single crystal X-ray diffraction. Compound 1 is orthorhombic, space group Pbcn, with a = 13.188(2) Å, b = 8.458(1) Å, c = 29.281(4) Å, V = 3266.2(7) Å3, D calc = 1.468 g/cm3, Z = 4, F(000) = 1476, R 1 = 0.0332. The [Co(NCS)4]2− anions form an unusual layer structure by S…N and S…Co interactions, while the [4NO2BzPy]+ cations stack into a 1D column by the p…π stacking interaction in the solid state of 1. A magnetic measurement in the range 2–300 K shows a weak antiferromagnetic exchange with θ = −2.42 K in 1.

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Authors and Affiliations

  1. Department of Applied Chemistry, Institute of Biomaterial, College of Science, South China Agricultural University, Guangzhou, P. R. China

    H. -Q. Ye, Y. -Y. Li, R. -K. Huang, X. -P. Liu, W. -Q. Chen, J. -R. Zhou, L. -M. Yang & C. -L. Ni

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  1. H. -Q. Ye
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  2. Y. -Y. Li
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  3. R. -K. Huang
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  4. X. -P. Liu
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  5. W. -Q. Chen
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  6. J. -R. Zhou
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  7. L. -M. Yang
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  8. C. -L. Ni
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Correspondence to J. -R. Zhou.

Additional information

Original Russian Text © 2014 H.-Q. Ye, Y.-Y. Li, R.-K. Huang, X.-P. Liu, W.-Q. Chen, J.-R. Zhou, L.-M. Yang, C.-L. Ni.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 4, pp. 725–730, July–August, 2014.

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Ye, H.Q., Li, Y.Y., Huang, R.K. et al. Unusual layer structure in an ion-paired compound containing tetra(isothiocyanate) cobalt(II) dianion and 4-nitrobenzylpyridinium: Crystal structure and magnetic properties. J Struct Chem 55, 691–696 (2014). https://doi.org/10.1134/S0022476614040143

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  • DOI: https://doi.org/10.1134/S0022476614040143

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