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Behavior of microporous zirconosilicate hilairite under high pressure

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Abstract

The behavior of natural zeolite-like hetero-framework zirconosilicate hilairite |Na1.47H0.53(H2O)2.7| [ZrSi3O9] is studied by single crystal X-ray diffraction at a high pressure (up to 4.73 GPa): space group R3, a = 10.5667(2) Å, c = 15.9109(4) Å, V = 1538.54(6) Å3, Z = 6. The compression of hilairite is practically isometric in the whole pressure range studied and is close to linear. Above 3.5 GPa an increasing deterioration of the single crystal is observed, which is interpreted as the started first order phase transition accompanied by significant volumetric changes.

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Authors and Affiliations

  1. Sobolev Institute of Geology and Mineralogy, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    Yu. V. Seryotkin

  2. Novosibirsk State University, Novosibirsk, Russia

    Yu. V. Seryotkin

  3. Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    V. V. Bakakin

  4. Faculty of Geology, Moscow State University, Moscow, Russia

    I. V. Pekov

Authors
  1. Yu. V. Seryotkin
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  2. V. V. Bakakin
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  3. I. V. Pekov
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Correspondence to Yu. V. Seryotkin.

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Original Russian Text © 2014 Yu. V. Seryotkin, V. V. Bakakin, I. V. Pekov.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 4, pp. 700–707, July–August, 2014.

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Seryotkin, Y.V., Bakakin, V.V. & Pekov, I.V. Behavior of microporous zirconosilicate hilairite under high pressure. J Struct Chem 55, 666–673 (2014). https://doi.org/10.1134/S0022476614040118

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  • DOI: https://doi.org/10.1134/S0022476614040118

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