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Crystal structure of polynuclear pivalate Ni(II) complexes with butanediol

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Abstract

Using single crystal X-ray diffraction the structure of polynuclear [Ni6(OH)4(Piv)7(HOC4H8O)(HPiv)4], {K4[Ni12(CO3)2(Piv)16(OH)8(HOC4H8OH)2]}HPiv, {[Ni6(OH)4(Piv)6(HOC4H8O)(Me2CO)(HOC4H8OH)2]4×(Piv)4}, and {K[Ni2L2(Piv)3]}∞ complexes, where HOC4H8OH is 1,4-butanediol, HPiv is pivalic acid, and L is the anion of nitroxyl radical 2,2,5,5-tetramethyl-4-(3′,3′,3′-trifluoro-2′-oxy-1′-propenyl)-3-imidazolin-1-oxyl is determined.

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Authors and Affiliations

  1. Institute of the International Tomography Center, Siberian Branch, Russian Academy of Sciences, Novosibirsk, Russia

    G. V. Romanenko, O. V. Kuznetsova, E. Yu. Fursova & V. I. Ovcharenko

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  1. G. V. Romanenko
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  2. O. V. Kuznetsova
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  3. E. Yu. Fursova
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  4. V. I. Ovcharenko
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Correspondence to G. V. Romanenko.

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Original Russian Text © 2014 G. V. Romanenko, O. V. Kuznetsova, E. Yu. Fursova, V. I. Ovcharenko.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 3, pp. 511–516, May–June, 2014.

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Romanenko, G.V., Kuznetsova, O.V., Fursova, E.Y. et al. Crystal structure of polynuclear pivalate Ni(II) complexes with butanediol. J Struct Chem 55, 481–487 (2014). https://doi.org/10.1134/S0022476614030135

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  • DOI: https://doi.org/10.1134/S0022476614030135

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