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Crystal structure and magnetic properties of hybrid materials self-assembled from the tetrakis(isothiocyanate)cobaltate(II) anion and trisubstituted benzyltriphenylphosphinium

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Abstract

A new hybrid material [BiF4BrBzTPP]2[Co(NCS)4] (1) (BiF4BrBzTPP+ = 2,6-bisfluoro-4-bromobenzyl-triphenylphosphinium, NCS− = isothiocyanate) is synthesized and characterized by elemental analyses, IR, UV spectra, ESI-MS, molar conductivity, single crystal X-ray diffraction and magnetic susceptibility measurements. Compound 1 crystallizes in the monoclinic space group C2/c with a = 15.272(2) Å, b = 24.779(3) Å, c = 14.482(2) Å, β = 101.037(2)°, V = 5378.9(12) Å3, Z = 4. The compound comprises two cations and one anion which exhibits a distorted tetrahedral coordination geometry. The short F...F, C...Br, and N...Br interactions and C-H...S hydrogen bonds consolidate the stacking of the molecules. Magnetic susceptibility measurements in the temperature range 2–300 K show that 1 exhibits weak antiferromagnetic coupling behavior.

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References

  1. M. Ohba and H. Okawa, Coord. Chem. Rev., 198, 313 (2000).

    Article  CAS  Google Scholar 

  2. L. K. Minacheva, I. S. Ivanova, A. Y. Tsivadze, et al., Russ. J. Inorg. Chem., 47, 1301 (2002).

    Google Scholar 

  3. T. H. Noh, J. H. Kim, Y. A. Lee, et al., J. Mol. Struct., 691, 165 (2003).

    Article  Google Scholar 

  4. D. P. Martin, W. R. Knapp, R. M. Supkowski, et al., Inorg. Chim. Acta, 362, 1559 (2009).

    Article  CAS  Google Scholar 

  5. C. L. Ni, Y. Z. Li, and Q. J. Meng, J. Coord. Chem., 58, 759 (2005).

    Article  CAS  Google Scholar 

  6. X. Chen, W. T. Yin, Q. Huang, et al., Transit. Met. Chem., 35, 143 (2010).

    Article  CAS  Google Scholar 

  7. X. Chen, J. H. Lin, H. L. Zhou, et al., Inorg. Chim. Acta, 363, 4024 (2010).

    Article  CAS  Google Scholar 

  8. J. R. Zhou, C. L. Ni, and L. L. Yu, Inorg. Chim. Acta, 361, 400 (2008).

    Article  CAS  Google Scholar 

  9. X. Chen, W. Q. Chen, S. Han, et al., J. Mol. Struct., 984, 164 (2010).

    Article  CAS  Google Scholar 

  10. R. Broos and M. Anteunis, Synth. Commun., 6, 53 (1976).

    Article  CAS  Google Scholar 

  11. G. M. Sheldrick, SHELXTL, Bruker AXS Inc Madison (1997).

    Google Scholar 

  12. K. Nakamoto, Infrared and Raman Spectra of Organic and Coordination Compound, 3rd Edition, Wiley, New York, USA (1978).

    Google Scholar 

  13. S. Banerjee, A. Ray, S. Sen, et al., Inorg. Chim. Acta, 361, 2692 (2008).

    Article  CAS  Google Scholar 

  14. W. J. Geary, Coord. Chem. Rev., 7, 81 (1971).

    Article  CAS  Google Scholar 

  15. H. J. Chen, L. Z. Zhang, Z. G. Cai, et al., J. Chem. Soc., Dalton Trans., 2463 (2000).

    Google Scholar 

  16. R. J. Baker, P. E. Colavita, D. M. Murphy, et al., J. Phys. Chem., 116, 1435 (2012).

    Article  CAS  Google Scholar 

  17. S. R. Halper and S. M. Cohen, Inorg. Chem., 44, 4139 (2005).

    Article  CAS  Google Scholar 

  18. M. Barcelo-Oliver, C. Estarellas, A. Garcia-Raso, et al., Crystengcomm., 12, 3758 (2010).

    Article  CAS  Google Scholar 

  19. C. F. Matta, N. Castillo, and R. J. Boyd, J. Phys. Chem., 109, 3669 (2005).

    Article  CAS  Google Scholar 

  20. Y. Wei, K. Wu, R. Broer, et al., Inorg. Chem. Commun., 10, 910 (2007).

    Article  CAS  Google Scholar 

  21. B. L. Li, X. Y. Wang, X. Zhu, et al., Polyhedron, 26, 5219 (2007).

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Applied Chemistry, College of Science, Institute of Biomaterials, South China Agricultural University, Guangzhou, P. R. China

    S. -L. Dai, Z. -P. Cheng, R. -K. Huang, Q. -Y. Guan, Y. -J. Liang, W. -Q. Huang, J. -R. Zhou & C. -L. Ni

Authors
  1. S. -L. Dai
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  2. Z. -P. Cheng
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  3. R. -K. Huang
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  4. Q. -Y. Guan
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  5. Y. -J. Liang
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  6. W. -Q. Huang
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  7. J. -R. Zhou
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  8. C. -L. Ni
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Corresponding author

Correspondence to C. -L. Ni.

Additional information

Original Russian Text © 2014 S.-L. Dai, Z.-P. Cheng, R.-K. Huang, Q.-Y. Guan, Y.-J. Liang, W.-Q. Huang, J.-R. Zhou, C.-L. Ni.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 2, pp. 395–399, March–April, 2014.

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Dai, S.L., Cheng, Z.P., Huang, R.K. et al. Crystal structure and magnetic properties of hybrid materials self-assembled from the tetrakis(isothiocyanate)cobaltate(II) anion and trisubstituted benzyltriphenylphosphinium. J Struct Chem 55, 374–378 (2014). https://doi.org/10.1134/S0022476614020292

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  • DOI: https://doi.org/10.1134/S0022476614020292

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