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Crystal and molecular structure of 1-(3-ammoniopropyl)silatrane chloride

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Abstract

By single crystal X-ray diffraction the crystal and molecular structure of 1-(3-ammoniopropyl)silatrane chloride (I) is determined. One of three cations in the asymmetric unit of the crystal of I differs from the other two by the length of the coordination N → Si bond. The opposite electronic effects in two geometrically similar cations are transferred inductively through a three-carbon chain.

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Authors and Affiliations

  1. Favorsky Institute of Chemistry, Siberian Branch, Russian Academy of Sciences, Irkutsk, Russia

    M. G. Voronkov, Yu. I. Bolgova & O. M. Trofimova

  2. East Siberian State Academy of Education, Irkutsk, Russia

    È. A. Zel’bst

  3. Saint-Petersburg State Institute of Technology, Saint-Petersburg, Russia

    V. S. Fundamensky & V. V. Gurzhiy

Authors
  1. M. G. Voronkov
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  2. È. A. Zel’bst
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  3. V. S. Fundamensky
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  4. V. V. Gurzhiy
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  5. Yu. I. Bolgova
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  6. O. M. Trofimova
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Corresponding author

Correspondence to È. A. Zel’bst.

Additional information

Original Russian Text © 2014 M. G. Voronkov, È. A. Zel’bst, V. S. Fundamensky, V. V.Gurzhiy, Yu. I. Bolgova, O. M. Trofimova.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 2, pp. 392–394, March–April, 2014.

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Voronkov, M.G., Zel’bst, È.A., Fundamensky, V.S. et al. Crystal and molecular structure of 1-(3-ammoniopropyl)silatrane chloride. J Struct Chem 55, 370–373 (2014). https://doi.org/10.1134/S0022476614020280

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  • DOI: https://doi.org/10.1134/S0022476614020280

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