Abstract
Novel mixed salts of the paratungstate anion Na2(NH4)8[H2W12O42]·12H2O (1) and Na7.5K2.5[H2W12O42]··22.2H2O (2) are obtained by slow concentration of tungstate solutions and characterized by single crystal X-ray diffraction.
Similar content being viewed by others
References
A. Müller and P. Kögerler, Coord. Chem. Rev., 199, No. 1, 335 (2000).
D. L. Long, E. Burkholder, and L. Cronin, Chem. Soc. Rev., 36, No. 1, 105 (2007).
C. Y. Sun, S. X. Liu, D. D. Liang, et al., J. Am. Chem. Soc., 131, No. 5, 1883 (2009).
C. Giménez-Saiz, J. R. Galán-Mascarós, S. Triki, et al., Inorg. Chem., 34, No. 2, 524 (1995).
B. Z. Lin, Y. M. Chen, and P. D. Liu, Dalton Trans., No. 12, 2474 (2003).
B. Li, L. H. Bi, W. Li, et al., J. Solid State Chem., 181, No. 12, 3337 (2008).
M. N. Sokolov, S. A. Adonin, P. A. Abramov, et al., Chem. Commun., 48, No. 53, 6666 (2012).
M. N. Sokolov, S. A. Adonin, E. V. Peresypkina, et al., Dalton Trans., 41, No. 39, 11978 (2012).
G. M. Sheldrick, SADABS, Program for Empirical X-ray Absorption Correction, Bruker-Nonius (1990).
Bruker, SHELXTL, Version 6.22. Bruker AXS Inc. Madison, WI, USA (2003).
J. J. Cruywagen and I. F. J. van der Merwe, J. Chem. Soc. Dalton Trans., No. 7, 1701 (1987).
A. Chrissafidou, J. Fuchs, H. Hartl, et al., Z. Naturforsch. B, 50, No. 2, 217 (1995).
H. d’Amour and R. Allmann, Z. Kristallogr., 138, No. 1, 5 (1973).
L. Yuan, C. Qin, X. Wang, et al., Z. Naturforsch. B, 63, No. 10, 1175 (2008).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2014 E. V. Peresypkina, A. V. Virovets, S. A. Adonin, P. A. Abramov, A. V. Rogachev, P. L. Sinkevich, V. S. Korenev, M. N. Sokolov.
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 2, pp. 315–318, March–April, 2014.
Rights and permissions
About this article
Cite this article
Peresypkina, E.V., Virovets, A.V., Adonin, S.A. et al. Crystal structure of two salts derived from paratungstate in the [H2W12O42]10− anion. J Struct Chem 55, 295–298 (2014). https://doi.org/10.1134/S0022476614020152
Received:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476614020152