Abstract
New multicomponent condensation of dimedone, benzaldehyde, acetacetic ester, and allylamine in the 1:2:1:1 molar ratio respectively is revealed. It proceeds with the formation of ethyl-3(allylamino)-9,9-dimethyl-7,11-dioxo-1.5-diphenyl-spiro[5.5]undec-2-en-2-carboxylate whose crystal structure is determined by single crystal X-ray diffraction.
References
L. F. Tietze, Chem. Rev., 96, No. 1, 115 (1996).
C. Simon, T. Constantieux, and J. Rodriquez, Eur. J. Org. Chem., 24, 4957 (2004).
V. V. Lipson, S. M. Desenko, V. V. Borodina, et al., Zh. Org. Khim., 41, No. 1, 115 (2005).
N. G. Kozlov, A. B. Tereshko, and K. N. Gusak, Zh. Org. Khim., 43, No. 9, 1375 (2007).
L. V. Frolova, I. Malik, P. Y. Uglinski, et al., Tetrahedron Lett., 52, No. 49, 6643 (2011).
C. Muchopadhyay, S. Rana, R. J. Butcher, et al., Tetrahedron Lett., 52, No. 44, 5835 (2011).
V. V. Lipson, N. V. Svetlichnaya, V. V. Borodina, et al., Zh. Org. Khim., 48, No. 2, 281 (2012).
C. G. Evans and J. E. Gestwicki, Org. Lett., 11, No. 14, 2957 (2009).
M. I. Kazantseva, Hantzsch Reaction in a Series of Acetylacetic Acid Esters and Amides; Biological Activity of the Obtained Compounds [in Russian], Diss. ... Cand. Pharm. Sc., Perm State Pharmaceutical Academy, Perm (2012).
G. M. Sheldrick, SHELXTL v.6.12, Structure Determination Software Suite, Brüker AXS, Madison, Wisconsin, USA (2001).
D. Cremer and J. A. Pople, J. Am. Chem. Soc., 97, No. 6, 1354 (1975).
F. H. Allen, D. G. Watson, L. Brammer, et al., Internat. Tables Crystallogr., Vol. C, Chapter 9.5, 790–811 (2006).
A. S. Kozmin, K. A. Potekhin, V. V. Shcherbukhin, et al., New J. Chem., 18, No. 6, 675 (1994).
Yu. T. Struchkov and K. A. Potekhin, J. Mol. Struct., 374, 259 (1996).
Yu. V. Zefirov and P. M. Zorkii, Usp. Khim., 58, No. 5, 713 (1989).
Author information
Authors and Affiliations
Corresponding author
Additional information
Original Russian Text © 2014 A. M. Magerramov, A. I. Ismiev, K. A. Potekhin, R. K. Askerov.
__________
Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 155–157, January–February, 2014.
Rights and permissions
About this article
Cite this article
Magerramov, A.M., Ismiev, A.I., Potekhin, K.A. et al. Molecular and crystal structure of ethyl-3(allylamino)-9,9-dimethyl-7,11-dioxo-1,5-diphenylspiro [5.5]undec-2-en-2-carboxylate. J Struct Chem 55, 151–153 (2014). https://doi.org/10.1134/S0022476614010260
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1134/S0022476614010260