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Crystal structure of [Pd3(μ-OH)(μ-CH3COO)5]

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Abstract

The crystals of the [Pd3(μ-OH)(μ-CH3COO)5] complex are obtained and characterized using powder and single crystal X-ray diffraction and IR spectroscopy. The crystal structure (a = 15.6942(6) Å, b = 11.7190(3) Å, c = 9.7871(3) Å, V = 1800.05(10) Å3, space group Pna21, Z = 4) is formed from neutral trinuclear cyclic molecules of [Pd3(μ-OH)(μ-CH3COO)5], in which the OH− group, together with five CH3COO− anions, is a bridge ligand.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    V. V. Tatarchuk, A. P. Sergievskaya, N. V. Kuratieva, I. V. Korol’kov, L. A. Sheludyakova & S. A. Gromilov

  2. Novosibirsk State University, Novosibirsk, Russia

    N. V. Kuratieva & S. A. Gromilov

Authors
  1. V. V. Tatarchuk
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  2. A. P. Sergievskaya
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  3. N. V. Kuratieva
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  4. I. V. Korol’kov
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  5. L. A. Sheludyakova
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  6. S. A. Gromilov
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Correspondence to S. A. Gromilov.

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Original Russian Text © 2014 V. V. Tatarchuk, A. P. Sergievskaya, N. V. Kuratieva,, I. V. Korol’kov, L. A. Sheludyakova, S. A. Gromilov.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 147–150, January–February, 2014.

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Tatarchuk, V.V., Sergievskaya, A.P., Kuratieva, N.V. et al. Crystal structure of [Pd3(μ-OH)(μ-CH3COO)5]. J Struct Chem 55, 142–146 (2014). https://doi.org/10.1134/S0022476614010247

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  • DOI: https://doi.org/10.1134/S0022476614010247

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