Skip to main content
SpringerLink
Log in

Crystal structures of bis(AZIDO)bis(2-morpholin-4-ylethylamino)copper(II) and bis{2,4-dibromo-6-[(2-morpholin-4-ylethylimino)methyl] phenolato}copper(II)

  • Brief Communications
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Two new copper(II) complexes [Cu(MEA)2(N3)2] (1) and [Cu(BMP)2] (2), where MEA and BMP are 2-morpholin-4-ylethylamine and 2,4-dibromo-6-[(2-morpholin-4-ylethylimino)methyl]phenolate respectively, are prepared and characterized using elemental analysis, FT-IR spectroscopy, and X-ray single crystal diffraction. The crystal of 1 belongs to the triclinic system, space group P-1, with a = 6.661(2) Å, b = 8.440(3) Å, c = 8.913(3) Å, α = 102.032(3)°, β = 107.899(2)°, γ = 98.242(3)°, V = 454.6(3) Å3, Z = 1, D c = 1.490 g/cm3, R 1 = 0.0226, and wR 2 = 0.0564. The crystal of 2 belongs to the monoclinic system, space group P21/c, with α = 7.0707(7) Å, b = 15.438(1) Å, c = 14.227(1) Å, β = 96.659(2)°, V = 1542.5(3) Å3, Z = 2, D c = 1.821 g/cm3, R 1 = 0.0437, and wR 2 = 0.1041. In each complex, the Cu atom is in a square planar coordination. The molecules of 1 are linked through intermolecular N-H...N and N-H...O hydrogen bonds to form layers parallel to the ab plane. The molecules of 2 are linked through intermolecular C-H...Br hydrogen bonds to form a 3D network.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. A. A. Hoser, W. Schilf, A. S. Chelmieniecka, B. Kolodziej, B. Kamienski, E. Grech, and K. Wozniak, Polyhedron, 31, No. 1, 241–248 (2012).

    Article  CAS  Google Scholar 

  2. H. Y. Liu, G. W. Li, Z. L. Li, J. Y. Wu, and Y. C. Cai, Russ. J. Coord. Chem., 37, No. 9, 668–673 (2011).

    Article  CAS  Google Scholar 

  3. Z.-L. You, D.-H. Shi, J.-C. Zhang, Y.-P. Ma, C. Wang, and K. Li, Inorg. Chim. Acta, 384, No. 1, 54–61 (2012).

    Article  CAS  Google Scholar 

  4. S. K. Dey, M. S. El Fallah, J. Ribas, T. Matsushita, V. Gramlich, and S. Mitra, Inorg. Chim. Acta, 357, No. 5, 1517–1522. (2004)

    Article  CAS  Google Scholar 

  5. D. Parker, E. S. Davies, C. Wilson, and J. McMaster, Inorg. Chim. Acta, 360, No. 1, 203–211 (2007).

    Article  CAS  Google Scholar 

  6. G. Murtaza, M. K. Rauf, A. Badshah, M. Ebihara, M. Said, M. Gielen, D. de Vos, E. Dilshad, and B. Mirza, Eur. J. Med. Chem., 48, No. 1, 26–35 (2012).

    Article  CAS  Google Scholar 

  7. B. Roopashree, V. Gayathri, and H. Mukund, J. Coord. Chem., 65, No. 8, 1354–1370 (2012).

    Article  CAS  Google Scholar 

  8. N. Raman, A. Kulandaisamy, and C. Thangaraja, Transition Met. Chem., 29, No. 2, 129–135 (2004).

    Article  CAS  Google Scholar 

  9. L. D. Popov, S. I. Levchenkov, M. A. Kiskin, I. N. Shcherbakov, Y. P. Tupolova, O. V. Maevskii, and V. A. Kogan, J. Struct. Chem., 53, No. 2, 393–396 (2012).

    Article  CAS  Google Scholar 

  10. D. Saha, T. Maity, T. Dey, and S. Koner, Polyhedron, 35, No. 1, 55–61 (2012).

    Article  CAS  Google Scholar 

  11. P. Seppala, E. Colacio, A. J. Mota, and R. Sillanpaa, Dalton Trans., 41, No. 9, 2648–2658 (2012).

    Article  CAS  Google Scholar 

  12. Bruker, SMART and SAINT, Bruker AXS Inc., Madison, Wisconsin, USA (2002).

  13. G. M. Sheldrick, SADABS, Univ. Göttingen, Germany (1996).

    Google Scholar 

  14. G. M. Sheldrick, SHELXS-97, Univ. Göttingen, Germany (1997).

    Google Scholar 

  15. G. M. Sheldrick, SHELXL-97, Univ. Göttingen, Germany (1997).

    Google Scholar 

  16. W. Geary, Coord. Chem. Rev., 7, Nos. 1/2, 81–122 (1971).

    Article  CAS  Google Scholar 

  17. Y.-Q. Cui, Z.-L. You, X.-F. Li, X.-L. Wang, Y.-P. Ma, C. Wang, and C.-L. Zhang, Transition Met. Chem., 35, No. 2, 159–163 (2010).

    Article  CAS  Google Scholar 

  18. B. Sarkar, M. S. Ray, M. G. B. Drew, C.-Z. Lu, and A. Ghosh, J. Coord. Chem., 60, No. 20, 2165–2176 (2007).

    Article  CAS  Google Scholar 

  19. C. Adhikary, D. Mal, K. Okamoto, S. Chaudhuri, and S. Koner, Polyhedron, 25, No. 11, 2191–2197 (2006).

    Article  CAS  Google Scholar 

  20. M. Zbiri, S. Saha, C. Adhikary, S. Chaudhuri, C. Daul, and S. Koner, Inorg. Chim. Acta, 359, No. 4, 1193–1199 (2006).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, Zhongshan, P. R. China

    H. -Y. Liu

Authors
  1. H. -Y. Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to H. -Y. Liu.

Additional information

Original Russian Text © 2014 H.-Y. Liu.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 139–143, January–February, 2014.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, H.Y. Crystal structures of bis(AZIDO)bis(2-morpholin-4-ylethylamino)copper(II) and bis{2,4-dibromo-6-[(2-morpholin-4-ylethylimino)methyl] phenolato}copper(II). J Struct Chem 55, 134–138 (2014). https://doi.org/10.1134/S0022476614010223

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S0022476614010223

Keywords

Search

Navigation