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Crystal structure of a Mn(II) complex with isatin-hydrazone-S-benzyldithiocarbazate

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Abstract

The reaction of Mn(OAc)2·4H2O with isatin-hydrazone-S-benzyldithiocarbazate (HIsa-SBn) results in the formation of a bis-ligand complex [Mn(Isa-SBn)2]·2DMF. Its single crystal is obtained and the structure is determined by X-ray diffraction. It belongs to a monoclinic space group C2/c with the cell parameters: a = 23.290(4) Å, b = 11.4980(18) Å, c = 18.483(5) Å, V = 4087.6(14) Å3. The Mn(II) atom is six-coordinated with two amide O atoms, two azomethine N atoms, and two thiolate S atoms, resulting in a distorted octahedral geometry.

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  1. School of Materials and Chemical Engineering Anhui University of Architecture, Hefei, P. R. China

    J. -J. Xia

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Original Russian Text © 2014 J.-J. Xia.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 135–138, January–February, 2014.

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Xia, J.J. Crystal structure of a Mn(II) complex with isatin-hydrazone-S-benzyldithiocarbazate. J Struct Chem 55, 130–133 (2014). https://doi.org/10.1134/S0022476614010211

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  • DOI: https://doi.org/10.1134/S0022476614010211

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