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Crystal structure of catena-(2-thiobarbiturato) dithallium(I)

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Abstract

By powder X-ray diffraction the crystal structure of catena-(2-thiobarbiturato)dithallium(I) C4H2N2O2STl2 (C4H4N2O2S is 2-thiobarbituric acid, H2TBA), Tl2TBA, is determined. Crystallographic data for Tl2TBA are as follows: a = 15.1039(3) Å, b = 12.0818(2) Å, c = 3.86455(6) Å, β = 97.203(1)°, V = 741.34(2) Å3, space group P21/n, Z = 4. There are two non-equivalent thallium atoms in the structure. The Tl1 polyhedron is a distorted trigonal prism due to the shortened Tl-S contact (3.634 Å), and the Tl2 polyhedron is a distorted square antiprism.

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Authors and Affiliations

  1. Siberian Federal University, Krasnoyarsk, Russia

    N. N. Golovnev

  2. L.V. Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Russia

    M. S. Molokeev

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  1. N. N. Golovnev
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  2. M. S. Molokeev
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Correspondence to N. N. Golovnev.

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Original Russian Text © 2014 N. N. Golovnev, M. S. Molokeev.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 130–134, January–February, 2014.

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Golovnev, N.N., Molokeev, M.S. Crystal structure of catena-(2-thiobarbiturato) dithallium(I). J Struct Chem 55, 125–129 (2014). https://doi.org/10.1134/S002247661401020X

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