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Structure and photoluminescent property of a three-dimensional pillared-layer La(III)-Cu(I) heterometallic coordination polymer

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Abstract

A three-dimensional (3D) pillared-layer La(III)-Cu(I) heterometallic coordination polymer (HCP) formulated as [La2Cu4I3(Hina)7(H2O)] n (1) (Hina = isonicotinic acid), is synthesized by a hydrothermal reaction of La2O3, CuI, and ina. The crystal structure is determined by single crystal X-ray diffraction. HCP 1 crystallizes in the monoclinic space group P21/c with unit cell parameters: a = 17.0147(3) Å, b = 18.4431(3) Å, c = 16.7487(3) Å, β = 102.469(2)°, V = 5131.84(15) Å3, Z = 4. It features a 3D pillared-layer heterometallic organic framework, where Ln-ina layers are pillared by discrete [Cu8I6(ina)12] units along the direction of the a axis. In addition, the solid-state photoluminescent property is investigated.

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Authors and Affiliations

  1. Department of Chemistry, Zunyi Normal College, Zunyi, P. R. China

    X. Li, H. Zhao & Q. Zeng

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  1. X. Li
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  2. H. Zhao
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  3. Q. Zeng
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Correspondence to X. Li.

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Original Russian Text © 2014 X Li, H. Zhao, Q. Zeng.

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 55, No. 1, pp. 101–105, January–February, 2014.

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Li, X., Zhao, H. & Zeng, Q. Structure and photoluminescent property of a three-dimensional pillared-layer La(III)-Cu(I) heterometallic coordination polymer. J Struct Chem 55, 96–100 (2014). https://doi.org/10.1134/S0022476614010156

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  • DOI: https://doi.org/10.1134/S0022476614010156

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