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Kinetics of the formation of Liesegang rings

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TO THE MEMORY OF R. E. LIESEGANG AND 75th ANNIVERSARY OF THE BOOK “PHYSICOCHEMICAL PERIODIC PROCESSES” WRITTEN BY F. M. SHEMYAKIN AND P. F. MIKHALEV

Abstract

The kinetics of the formation of Liesegang rings is considered and they are classified. The relationship between the position of the propagating diffusion front and the moments of the formation of Liesegang rings is shown. In order to describe the formation processes of the Liesegang rings a generalized model based on the diffusion equation hierarchy is proposed. The kinetics of changes in the dispersed phase sizes at the initial stage of the formation of Liesegang rings is studied.

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Correspondence to D. L. Tytik.

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Original Russian Text © 2013 V. I. Kuz’min, A. F. Gadzaov, D. L. Tytik, S. A. Busev, A. A. Revina, V. V. Vysotskii.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, Supplement 2, pp. S368–S382, 2013.

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Kuz’min, V.I., Gadzaov, A.F., Tytik, D.L. et al. Kinetics of the formation of Liesegang rings. J Struct Chem 54 (Suppl 2), 363–378 (2013). https://doi.org/10.1134/S0022476613080167

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  • DOI: https://doi.org/10.1134/S0022476613080167

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