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Manifestation of ion specificity in the behavior of the dynamic dielectric permittivity of aqueous solutions of alkali metal halides

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Abstract

Dispersions of the refractive index are measured in aqueous solutions of potassium halides at different salt concentrations and temperatures of the solutions. The specific effect of anions on the dynamic dielectric permittivity of the solutions is found. A model is proposed to evaluate the character of changes in the dynamic dielectric permittivity of the solutions and effective dynamic polarizabilities of ions in the solutions based on the data about the dispersion of refractive indices. The role of ion sizes and the character of their interaction with a solvent in the manifestation of specific ion effects are discussed.

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References

  1. F. Hofmeister, Arch. Exp. Pathol. Pharmakol., 24, 247 (1888).

    Article  Google Scholar 

  2. W. Kunz, J. Henle, and B. W. Ninham, Curr Opinop. Colloid Interface Sci., 9, 19–37 (2004).

    Article  CAS  Google Scholar 

  3. B. W. Ninham, P. Lo Nostro, Molecular Forces and Self Assembly in Colloid, Nano Sciences and Biology, Cambridge Molecular Science (2010), p. 146.

    Book  Google Scholar 

  4. J. L. Poiseuille, Ann. Chim. Phys., 21, 76–110 (1847).

    Google Scholar 

  5. W. Kunz (ed.), in: Specific Ion Effects, World Scientific Publishing (2010).

    Google Scholar 

  6. A. A. Zavitsas, J. Phys. Chem. B, 105, 7805–7817 (2001).

    Article  CAS  Google Scholar 

  7. H. Hosoda, H. Mori, N. Sogoshi, et al., J. Phys. Chem. A, 108, 1461–1464 (2004).

    Article  CAS  Google Scholar 

  8. T. Schleich and P. H. Von Hippel, Biopolymers, 7, 861–877 (1969).

    Article  CAS  Google Scholar 

  9. A. P. Dos Santos, A. Diehl, and Y. Levin, Langmuir, 26, 10778–10783 (2010).

    Article  Google Scholar 

  10. J. M. Borah, S. Mahiuddin, N. Sarma, et al., Langmuir, 27, 8710–8717 (2011).

    Article  CAS  Google Scholar 

  11. M. Bostreom, D. F. Parsons, A. Salis, et al., Langmuir, 27, 9504–9511 (2011).

    Article  Google Scholar 

  12. G. V. Franks, J. Colloid Interface Sci., 249, 44 (2002).

    Article  CAS  Google Scholar 

  13. G. V. Franks and L. Meagher, Colloids Surfaces A, 214, 99 (2003).

    Article  CAS  Google Scholar 

  14. D. F. Parsons and B. W. Ninham, Colloids and Surfaces A, 383, 2–9 (2011).

    Article  CAS  Google Scholar 

  15. D. F. Parsons and B. W. Ninham, Langmuir, 26, 1816–1823 (2010).

    Article  CAS  Google Scholar 

  16. B. V. Derjaguin, I. E. Dzyaloshinsky, M. M. Koptelova, et al., Disc. Faraday Soc., No. 40, 246–252 (1965).

    Google Scholar 

  17. Yu. S. Barash, Van der Waals Forces [in Russian], Nauka, Moscow (1988).

    Google Scholar 

  18. M. F. Kropman and H. J. Bakker, Science, 291, 2118 (2001).

    Article  CAS  Google Scholar 

  19. S. Raugei and M. L. Klein, J. Chem. Phys., 116, 196–202 (2002).

    Article  CAS  Google Scholar 

  20. W. R. Fawcett, Liquids, Solutions, and Interfaces: From Classical Macroscopic Descriptions to Modern Microscopic Details, Topics in Analytical Chemistry, Oxford University Press, New York (2004).

    Google Scholar 

  21. J.-H. Choi, K. T. Kuwata, Y. B. Cao, et al., J. Phys. Chem. A, 102, 503 (1998).

    Article  CAS  Google Scholar 

  22. P. Ayotte, C. G. Bailey, G. H. Weddle, et al., J. Phys. Chem., 103, 443 (1999).

    Article  CAS  Google Scholar 

  23. M. L. Klein, Science, 291, 2106 (2001).

    Article  CAS  Google Scholar 

  24. J. A. White, E. Schwegler, G. Galli, et al., J. Chem. Phys., 113, 4668 (2000).

    Article  CAS  Google Scholar 

  25. A. P. Lyubartsev, K. Laasonen, and A. Laaksonen, J. Chem. Phys., 114, 3120 (2001).

    Article  CAS  Google Scholar 

  26. L. B. Boinovich and A. M. Emelyanenko, Colloid J., 65, 672 (2003).

    Article  CAS  Google Scholar 

  27. L. D. Landau and E. M. Lifshits, Electrodynamics of Continuous Media [in Russian], V. 8, Nauka, Moscow (2002), pp. 409/410.

    Google Scholar 

  28. D. Henderson and M. Lozada-Cassou, J. Colloid Interface Sci., 162, 508 (1994).

    Article  CAS  Google Scholar 

  29. Y. Marcus, Pure & Appl. Chem., 59, 1093–1101 (1987).

    Article  CAS  Google Scholar 

  30. W. Kunz (ed.), in: Current Opinion in Colloid & Interface Science, 15, 34–39 (2010).

  31. B. W. Ninham and V. A. Parsegian, J. Chem. Phys., 52, 4578 (1970).

    Article  CAS  Google Scholar 

  32. D. B. Hough and L. R. White, Adv. Colloid Interface Sci., 14, 3 (1980).

    Article  CAS  Google Scholar 

  33. L. B. Boinovich and A. M. Emelłyanenko, Russ. Chem. Bull., 2, 263 (2008).

    Article  Google Scholar 

  34. T. Chen, G. Hefter, and R. Buchner, J. Phys. Chem. A, 107, 4025–4031 (2003).

    Article  CAS  Google Scholar 

  35. A. V. Kobelev, A. S Lileev., and A. K. Lyashchenko, Zh. Neorg. Khim., 56, No. 4, 697–704 (2011).

    Google Scholar 

  36. Ya. Yu. Akhadov, Dielectric Binary Solutions [in Russian], Nauka, Moscow (1977).

    Google Scholar 

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Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Moscow, France

    F. M. Shagieva & L. B. Boinovich

Authors
  1. F. M. Shagieva
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  2. L. B. Boinovich
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Correspondence to L. B. Boinovich.

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Original Russian Text © 2013 F. M. Shagieva, L. B. Boinovich.

__________

Translated from Zhurnal Strukturnoi Khimii, Vol. 54, Supplement 2, pp. S350–S359, 2013.

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Shagieva, F.M., Boinovich, L.B. Manifestation of ion specificity in the behavior of the dynamic dielectric permittivity of aqueous solutions of alkali metal halides. J Struct Chem 54 (Suppl 2), 345–354 (2013). https://doi.org/10.1134/S0022476613080143

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  • DOI: https://doi.org/10.1134/S0022476613080143

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