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Cluster structure of water in accordance with the data on dielectric permittivity and heat capacity

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Abstract

In the work the character of water clusterization in the whole existence domain of its liquid state is discussed: from supercooled states to the critical point. Conclusions about the cluster composition of liquid water are drawn based on the analysis: 1) of the features of dielectric relaxation; 2) character of the temperature dependence of its static dielectric permittivity, and 3) the value and temperature dependence of different contributions to the heat capacity of the system. It is shown that near the water crystallization point tetramers prevail in its structure, with an increase in the temperature trimers start to play the main role, and near the critical point of water dimers become the major associates. At temperatures near the water crystallization point the obtained results well agree with the data on emission and absorption X-ray spectroscopy.

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Authors and Affiliations

  1. I. I. Mechnikov Odessa National University, Odessa, Ukraine

    N. P. Malomuzh, V. N. Makhlaichuk & P. V. Makhlaichuk

  2. Institute of International Educational Programs, Odessa National Polytechnic University, Odessa, Ukraine

    K. N. Pankratov

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  1. N. P. Malomuzh
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  2. V. N. Makhlaichuk
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  3. P. V. Makhlaichuk
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  4. K. N. Pankratov
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Correspondence to N. P. Malomuzh.

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Original Russian Text © 2013 N. P. Malomuzh, V. N. Makhlaichuk, P. V. Makhlaichuk, K. N. Pankratov.

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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, Supplement 2, pp. S210–S225, 2013.

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Malomuzh, N.P., Makhlaichuk, V.N., Makhlaichuk, P.V. et al. Cluster structure of water in accordance with the data on dielectric permittivity and heat capacity. J Struct Chem 54 (Suppl 2), 205–220 (2013). https://doi.org/10.1134/S0022476613080039

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