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Single-crystal 1H NMR data and hydrogen atom disorder in lawsonite, CaAl2[Si2O7](OH)2·H2O

  • Current NMR and EPR Spectroscopy Methods in Structural Chemistry of Complex Crystals, Glasses, Composites, and Biological Membranes
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Abstract

The dynamic structure of hydrogen sublattice in lawsonite, CaAl2[Si2O7](OH)2·H2O is studied by the solidstate proton magnetic resonance (1H NMR) spectroscopy of single crystal at room temperature. It is shown that both encapsulated water molecules, and hydroxyl OH-groups undergoes the rocking librations of the amplitudes of ∼20° for H2O, and ∼40° for hydroxyls.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    S. G. Kozlova & S. P. Gabuda

Authors
  1. S. G. Kozlova
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  2. S. P. Gabuda
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Correspondence to S. G. Kozlova.

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Original Russian Text Copyright © 2013 by S. G. Kozlova, S. P. Gabuda

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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, Supplement 1, pp. S147–S151, 2013.

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Kozlova, S.G., Gabuda, S.P. Single-crystal 1H NMR data and hydrogen atom disorder in lawsonite, CaAl2[Si2O7](OH)2·H2O. J Struct Chem 54 (Suppl 1), 146–151 (2013). https://doi.org/10.1134/S0022476613070159

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  • DOI: https://doi.org/10.1134/S0022476613070159

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