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51V NMR in Mn2−2x Ni2x V2O7 solid solutions

  • Current NMR and EPR Spectroscopy Methods in Structural Chemistry of Complex Crystals, Glasses, Composites, and Biological Membranes
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Abstract

51V NMR, DTA, and thermogravimetric analysis are used to study the thermal behavior of a manganesenickel pyrovanadate complex Mn2−2x Ni2x V2O7. It is shown that the nature of 51V hyperfine interactions in manganese pyrovanadate and solid solutions based on its polymorphic modifications is specified by the structurally activated oxygen exchange with the gaseous phase.

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Division, Russian Academy of Sciences, Ekaterinburg, Russia

    N. A. Zhuravlev, M. V. Rotermel, T. I. Krasnenko & R. F. Samigullina

Authors
  1. N. A. Zhuravlev
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  2. M. V. Rotermel
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  3. T. I. Krasnenko
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  4. R. F. Samigullina
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Correspondence to N. A. Zhuravlev.

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Original Russian Text Copyright © 2013 by N. A. Zhuravlev, M. V. Rotermel, T. I. Krasnenko, R. F. Samigullina

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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, Supplement 1, pp. S128–S131, 2013.

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Zhuravlev, N.A., Rotermel, M.V., Krasnenko, T.I. et al. 51V NMR in Mn2−2x Ni2x V2O7 solid solutions. J Struct Chem 54 (Suppl 1), 126–129 (2013). https://doi.org/10.1134/S0022476613070123

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  • DOI: https://doi.org/10.1134/S0022476613070123

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