Skip to main content
SpringerLink
Log in

Crystal structures of aroylhydrazones derived from 5-methoxysalicylaldehyde

  • Brief Communications
  • Published:
Journal of Structural Chemistry Aims and scope Submit manuscript

Abstract

Two new aroylhydrazones 3-bromo-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide (1) and 4-hydroxy-3-methoxy-N′-(2-hydroxy-5-methoxybenzylidene)benzohydrazide (2), derived from 5-methoxysalicylaldehyde, are prepared and determined by means of infrared and 1H NMR spectroscopy and single crystal X-ray diffraction. Compound 1 crystallizes in the monoclinic space group P21/n with a = 5.9406(7) Å, b = 31.833(3) Å, c = 7.6460(8) Å, β = 94.522(4)°, V = 1441.4(3) Å3, Z = 4. Compound 2 crystallizes in the monoclinic space group P21/c with a = 14.3471(9) Å, b = 11.3893(7) Å, c = 9.6853(6) Å, β = 94.063(2)°, V = 1578.6(2) Å3, Z = 4. Both molecules have very similar bond lengths and angles. The crystal structures of both compounds are stabilized by N-H...O and O-H...O hydrogen bonds as well as π...π interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

References

  1. Y.-J. Wei and F.-W. Wang, J. Struct. Chem., 52, 755–759 (2011).

    Article  CAS  Google Scholar 

  2. Y. Lei, T.-Z. Li, C. Fu, et al., J. Chem. Crystallogr., 41, 1707–1711 (2011).

    Article  CAS  Google Scholar 

  3. H.-Y. Zhu, Asian J. Chem., 24, 558–560 (2012).

    CAS  Google Scholar 

  4. H. H. Monfared, S. Alavi, R. Bikas, et al., Polyhedron, 29, 3355–3362 (2010).

    Article  CAS  Google Scholar 

  5. D. Matoga, J. Szklarzewicz, K. Stadnicka, et al., Inorg. Chem., 46, 9042–9044 (2007).

    Article  CAS  Google Scholar 

  6. M. Kuriakose, M. R. P. Kurup, and E. Suresh, Struct. Chem., 18, 579–584 (2007).

    Article  CAS  Google Scholar 

  7. P. V. Bernhardt, P. Chin, and D. R. Richardson, J. Biol. Inorg. Chem., 6, 801–809 (2001).

    Article  CAS  Google Scholar 

  8. A. Walcourt, M. Loyevsky, D. B. Lovejoy, et al., Int. J. Biochem. Cell Biol., 36, 401–407 (2004).

    Article  CAS  Google Scholar 

  9. K. K. V. Raj, B. Narayana, B. V. Ashalatha, et al., Eur. J. Med. Chem., 42, 425–429 (2007).

    Article  CAS  Google Scholar 

  10. X. H. Peng, X. L. Tang, W. W. Qin, et al., Dalton Trans., 40, 5271–5277 (2011).

    Article  CAS  Google Scholar 

  11. A. A. Tameem, B. Saad, A. Makahleh, et al., Talanta, 82, 1385–1391 (2010).

    Article  CAS  Google Scholar 

  12. G. M. Sheldrick, SHELXL97, Program for Crystal Structure Refinement, Univ. Göttingen, Germany (1997).

    Google Scholar 

  13. J. Bernstein, R. E. Davis, L. Shimoni, et al., Angew. Chem. Int. Ed. Eng., 34, 1555–1573 (1995).

    Article  CAS  Google Scholar 

  14. A. B. P. Lever, Inorganic Electronic Spectroscopy, 2nd ed., Elsevier Science Publishers B.V., The Netherlands (1984).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. College of Biology and Chemical Engineering, Jiaxing University, Jiaxing Zhejiang, P. R. China

    Q. -S. Zong & J. -Y. Wu

  2. School of Pharmaceutical Sciences, Zhejiang University, Hangzhou Zhejiang, P. R. China

    Q. -S. Zong

Authors
  1. Q. -S. Zong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. -Y. Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Q. -S. Zong.

Additional information

Original Russian Text © 2013 Q.-S. Zong, J.-Y. Wu

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 54, No. 6, pp. 1121–1126, November–December, 2013.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Zong, Q.S., Wu, J.Y. Crystal structures of aroylhydrazones derived from 5-methoxysalicylaldehyde. J Struct Chem 54, 1151–1156 (2013). https://doi.org/10.1134/S002247661306022X

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1134/S002247661306022X

Keywords

Search

Navigation