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Crystal structures of methyl and benzyl 5-ferrocenyl-3,5-dimethyl-2-pyrazoline-1-dithiocarboxylate

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Abstract

Reactions of E-4-ferrocenylpent-3-en-2-one with S-methyldithiocarbazate or S-benzyldithiocarbazate result in the formation of methyl 5-ferrocenyl-3,5-dimethyl-2-pyrazoline-1-dithiocarboxylate (1) or benzyl 5-ferrocenyl-3,5-dimethyl-2-pyrazoline-1-dithiocarboxylate (2). The single crystals of both products are obtained and their structures are identified by X-ray diffraction method with triclinic P-1 space groups. The cell parameters for compound 1 are as follows: a = 7.7029(8) Å, b = 10.1631(11) Å, c = 10.7305(12) Å, α = 101.3270(10)°, β = 90.6740(10)°, γ = 94.8390(10)°, and V = 820.40(15) Å3. For compound 2, the crystallographic data are: a = 7.953(3) Å, b = 10.970(5) Å, c = 12.534(3) Å, α = 84.718(5)°, β = 81.651(3)°, γ = 76.274(4)Å, and V = 1049.1(7) Å3.

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Authors and Affiliations

  1. Department of Chemical Engineering, Yancheng Textile Vocational Technology College, Yancheng, P. R. China

    X. Zhu & D. -S. Xiang

  2. School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing, P. R. China

    X. Zhu

  3. School of Chemical and Biological Engineering, Yancheng Institute of Technology, Yancheng, P. R. China

    W. -Y. Shi

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  1. X. Zhu
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  2. D. -S. Xiang
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  3. W. -Y. Shi
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Correspondence to X. Zhu.

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Original Russian Text © 2013 X. Zhu, D.-S. Xiang, W.-Y. Shi

The text was submitted by the authors in English. Zhurnal Strukturnoi Khimii, Vol. 54, No. 6, pp. 1077–1081, November–December, 2013.

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Zhu, X., Xiang, D.S. & Shi, W.Y. Crystal structures of methyl and benzyl 5-ferrocenyl-3,5-dimethyl-2-pyrazoline-1-dithiocarboxylate. J Struct Chem 54, 1107–1111 (2013). https://doi.org/10.1134/S0022476613060152

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  • DOI: https://doi.org/10.1134/S0022476613060152

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