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Properties and structure of new volatile phenyl-containing β-diketonates of trimethylplatinum(IV): (CH3)3Pt(btfa)H2O, (CH3)3Pt(bac)Py, and initial complex [(CH3)3PtI]4

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Abstract

By interaction of trimethylplatinum(IV) iodide with phenyl-containing β-diketonates, the volatile monomeric complexes of trimethylplatinum(IV) based on benzoyltrifluoroacetone (Hbtfa) and benzoylacetone (Hbac) of the composition (CH3)3Pt(btfa)H2O (I) and (CH3)3Pt(bac)Py (II) are obtained. Synthesis of the complexes is described; data of elemental analysis and IR spectra are reported; thermal characteristics are studied by thermogravimetry. For the first time, a single crystal X-ray diffraction study of complexes (I), (II), and the initial tetrameric complex [(CH3)3PtI]4 (III) is performed.

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Authors and Affiliations

  1. A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division, Russian Academy of Sciences, Novosibirsk, Russia

    G. I. Zharkova, I. A. Baidina, A. I. Smolentsev & I. K. Igumenov

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  1. G. I. Zharkova
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  2. I. A. Baidina
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  3. A. I. Smolentsev
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  4. I. K. Igumenov
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Correspondence to G. I. Zharkova.

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Original Russian Text © 2013 G. I. Zharkova, I. A. Baidina, A. I. Smolentsev, I. K. Igumenov

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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, No. 6, pp. 1052–1059, November–December, 2013.

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Zharkova, G.I., Baidina, I.A., Smolentsev, A.I. et al. Properties and structure of new volatile phenyl-containing β-diketonates of trimethylplatinum(IV): (CH3)3Pt(btfa)H2O, (CH3)3Pt(bac)Py, and initial complex [(CH3)3PtI]4 . J Struct Chem 54, 1083–1090 (2013). https://doi.org/10.1134/S0022476613060127

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  • DOI: https://doi.org/10.1134/S0022476613060127

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