Abstract
Spin transition theory is developed for periodic chains with two and more exchange clusters in a unit cell. A general expression is obtained for the effective magnetic moment of a unit cell μeff with several exchange clusters. For heterospin complexes Cu(hfac)2LR characterized by chains with the head-to-head motif a twosite approximation for the statistical sum of the Cu2+ Jahn-Teller paramagnetic center Cu2+ with spin 1/2 is proposed, within which a comparison with the available experimental data is performed. It is shown that the model developed describes both smooth and abrupt (cooperative) spin-crossover cases for the chains of three-spin exchange clusters.
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Original Russian Text © 2013 V. A. Morozov
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Translated from Zhurnal Strukturnoi Khimii, Vol. 54, No. 6, pp. 965–971, November–December, 2013.
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Morozov, V.A. Description of spin-crossover in a heterogeneous chain of exchange clusters. J Struct Chem 54, 997–1003 (2013). https://doi.org/10.1134/S0022476613060012
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DOI: https://doi.org/10.1134/S0022476613060012