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Journal of Structural Chemistry

, Volume 54, Issue 4, pp 820–823 | Cite as

Crystal structure of bis[Ba(Aet)(OH2)5]bis(Aet)·4H2O

  • È. B. MiminoshviliEmail author
  • K. È. Miminoshvili
  • L. A. Beridze
  • S. R. Zazishvili
Brief Communications
  • 42 Downloads

Abstract

An X-ray crystallographic study is conducted of single crystals with the composition [Ba2(Aet)2·10(H2O)]2+·2(Aet)·4H2O, where Aet = (C10H11N4O2S2) is the ethazole (2-(para-aminobenzenesulfamido)-5-ethyl-1,3,4-tiadiazole) anion. The crystals are monoclinic; the space group is P21/c, Z = 2; a = 9.793(2) Å, b = 15.408(4) Å, and c = 22.553(6) Å; β = 94.98(2)°; and R = 0.047. The independent part of the compound’s structural formula, [Ba(Aet)(OH2)5](Aet)·2H2O, is isostructural with the analogous compound with the Sr atom. The ethazole anion is coordinated to the complexing metal atom by oxygen and nitrogen atoms to form a four-membered ring.

Keywords

complex compounds X-ray crystallography Ba(II) Sr(II) ethazole sulfanilamides 

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References

  1. 1.
    È. B. Miminoshvili, K. È. Miminoshvili, L. A. Beridze, and S. R. Zazishvili, J. Struct. Chem., 51, No. 1, 181–186 (2010).CrossRefGoogle Scholar
  2. 2.
    G. M. Sheldrick, User Manual, Revision 4, Nicolet XRD Corporation, USA (1983).Google Scholar
  3. 3.
    S. Chantrapromma, A. Usman, and H.-K. Fun, Acta Crystallogr., C58, m531–m533 (2002).Google Scholar
  4. 4.
    S. M. F. Lo, S. S. Y. Chui, and I. D. Williams, Acta Crystallogr., C54, 1846–1848 (1998).Google Scholar
  5. 5.
    R. López Garzón, M. L. Godino Salido, J. N. Low, and C. Glidewell, Acta Crystallogr., C59, m255–m258 (2003).Google Scholar
  6. 6.
    S. Djehni, F. Balegroune, A. Guehria-Laidoudi, S. Dahaoui, and C. Lecomty, Acta Crystallogr., C63, m91–m93 (2007).Google Scholar
  7. 7.
    È. B. Miminoshvili, K. È. Miminoshvili, and L. A. Beridze, J. Struct. Chem., 50, No. 1, 170–175 (2009).CrossRefGoogle Scholar

Copyright information

© Pleiades Publishing, Ltd. 2013

Authors and Affiliations

  • È. B. Miminoshvili
    • 1
    Email author
  • K. È. Miminoshvili
    • 1
  • L. A. Beridze
    • 2
  • S. R. Zazishvili
    • 2
  1. 1.Georgian Technical UniversityTbilisiGeorgia
  2. 2.Tbilisi State Medical UniversityTbilisiGeorgia

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